Establishment of the principle of the design of new opto-electro-fiinctional mataials by the control of the properties of silicon-containing compounds

本研究的目的是在利用特征反应精确控制硅氧键的一级和高级结构的基础上，通过控制含硅化合物的性质来设计光电功能材料。(1)首次研究了基于控制硅氧键的初级和高阶结构和性能的封装材料和新型功能材料的设计，即硅氧键的形成反应、微孔材料的形成、具有良好控制结构的三维倍半硅氧烷的形成以及利用液晶化合物的不相容来设计新的功能材料。(2)建立了基于控制硅氧键的初级和共轭特性的新型功能材料的设计原则(3)通过立体化学结构的控制来开发高性能材料。在本研究中，作者根据作者发现的最新的硅化合物反应进行了探讨。得到了各种有用的结果。其中，硅氧键的形成和硅烷与水的脱氢反应合成新型含硅氧烷聚合物是一个值得注意的高效独特的反应。另一个独特的结果是高效率光致发光材料的发展。光学活性SiB‘阴离子的开发及其在形成立体正则聚硅氧烷中的应用也是一个非常有价值的结果。该反应和产物被用于开发高性能材料。建立了具有可控结构的聚倍半硅氧烷形成的反应机理也是一个显著的结果。这些化合物被用于合成新型高性能聚硅氧烷聚合物和全息材料，很好地实现了本研究的初衷。较少

This research was carried out with the aim of the establishment of the principle to design opto-electro-functional materials by the control of the properties of silicon-containing compounds based on the precise control of the reaction and primary and higher order structure of silicon-oxygen bond using the characteristic reactions. Three objects were pursued.(1) Design of package materials and new functional materials based on the control of primary and higher order structure and properties of silicon-oxygen bond was firstly studied, namely development and refinement of the formation reaction of silicon-oxygen bond, formation of micro-porous materials, formation of three dimensional silsesquioxane with well-controlled structure, and usage of the incompatibility of liquid crystalline compounds in designing new functional materials.(2) Establishment of the principle to design new functional materials based on the control of the primary and conjugative characteristics of silicon-silicon bo … More nd, and(3) Development of high performance materials by the control of the stereo-chemical structure were studied.In this research, approach was made based on the newly developed reactions of silicon compounds found by the author. Various useful results were obtained. Among them, formation of silicon-oxygen bond, and the synthesis of new siloxane-containing polymers by the dehydrogenation reaction between silane and water is a notable highly efficient and unique reaction. Development of photo-luminescent material with high efficiency is another unique result. Development of optically active sib,' anion and its use in the formation of stereoregular polysiloxanes is also a highly valuable result. This reaction and the products were used to develop high performance materials. Establishment of the reaction mechanism of the formation of polysilsesquioxane with controlled structure is also a notable result. These compounds were used to create new high performance polysiloxanes polymers and holographic materials.Thus, the original aims of this research were well-achieved. Less