SCILL with mono- and bifunctional ionic liquids for selective hydrogenation reactions (C01)

C01项目涉及用带有一种或几种功能的il修饰氧化铝负载的Pt和Pd催化剂。通过IL及其官能与固体催化剂的特异性相互作用，期望产生一种类似配体的IL效应，这种效应强烈地改变了负载纳米颗粒活性位点的活性和选择性。ILs将以最高纯度制备，并提供给合作伙伴项目C02-C05。制备的催化剂将在竞争性气相加氢反应中进行测试，将SCILL体系与非功能化IL、功能化IL和IL混合物进行比较。该项目将提供先进SCILL催化剂的详细动力学数据（活性、选择性、化学选择性），并将探索反应条件下IL功能的稳定性。

Project C01 deals with the modification of alumina-supported Pt and Pd catalysts with ILs that carry one or several functionalities. By specific interaction of the IL and its functionalities with the solid catalyst, a ligand-like IL effect is expected which strongly alters activity and selectivity of the active sites of the supported nanoparticles. The ILs will be prepared in highest purity and are also provided to the partner projects C02–C05. The prepared catalysts will be tested in competitive gas phase hydrogenation reactions comparing SCILL systems with non-functionalised ILs, functionalised ILs and IL mixtures. This project will provide detailed kinetic data (activity, selectivity, chemoselectivity) of Advanced SCILL catalysts and will explore the stability of IL functionalities under reaction conditions.