NMR spectroscopic tools to detect Brønsted/Lewis acid-base preorganization in photocatalysis (B03)

该项目的主要目标是检测、合理化和设计氢键和刘易斯酸/碱相互作用在光催化中的作用。先进的核磁共振光谱方法结合来自合成合作伙伴的选定和设计的模型系统，将用于解决分离的氢键、协同效应和扩展的氢键网络在光催化中的影响。此外，对于迄今为止更灵活和更少定向的路易斯酸碱相互作用，应测试核磁共振光谱工具，以开发基于结构的路易斯酸碱光催化效应的途径。

The main goal of the project is to detect, rationalize and design the effect of H-bonds and Lewis-acid/base interactions in photocatalysis. Advanced NMR-spectroscopic methods in combination with selected and designed model systems from synthetic collaboration partners will be used to address the impact of isolated H-bonds, cooperativity effects and extended H-bond networks in photocatalysis. In addition, for the by far more flexible and less directed Lewis acid base interactions NMR spectroscopic tools shall be tested to develop an access to structure-based Lewis acid base effects in photocatalysis.