New Development of Organic Electrochemistry

这一组的调查{x00}起到了管理小组对这一研究项目的作用。该小组由6名顾问和5名执行成员组成，在四个研究小组(A01-A04)的密切合作下有效地推动了研究项目的开展。1.研究对象和结果本项目由4个研究课题组成：1)电子转移反应场的设计与控制(A01)，2)电生异常活性物种(A02)，3)中介反应的发展(A03)，4)配位化合物中电子转移的新进展(A04)。1995年，29名项目成员和91名公众申请成员参与了该项目。1996年10月，我们评价了所有学科取得的丰硕成果，不仅显著地发展了有机电化学，而且建立了许多常规有机化学方法无法完成的有机反应体系。此外，结果是c-…。更多地致力于建立协调化学和生物化学的跨学科领域。值得一提的是，在我们的初步提议的基础上，实现了不对称或对映选择性电解，成为有机化学中的一个新工具。2.全体会员会议和公开研讨会的开幕。6个全体会员会议和5个公开研讨会，管理小组和每个研究课题小组的多次会议。注意到，组长积极安排维护活性金属表面电极、物理方法电极反应、电子转移生物功能和手性合成四个非正式的合作研究系统。3.各成员每年年底发表日文和英文各2页的材料研究报告，并于1996年12月完成每个成员4页的集体研究报告。每次会员大会和公开座谈会的摘要不仅分发给会员和其他与会者，而且还向会员分发了12次与研究有关的新闻信。一本支持蒙布略的英文书《有机电化学的新挑战》正在筹备中，将于1998年2月出版。较少

Investigation of this group {X00} playd a function of managemet group for this rescarch project. The group consisted of 6 advisory and 5 executive members exerted an effective propulsion of the research project in close cooperation of four research groups (A01-A04) , getting advice by advisory members.1.Research Subjects and Ressults The project was set up by four research subjects : 1) Design and Control of Electron-transfer Reaction Fields (A01), 2) Electrogenerated Unusual Active Species (A02), 3) Development of Mediator Reactions (A03), and 4) New Development of Electron Transfer in Coordination Compounds (A04). The project was pursued by 29 project members and 91 public-applicant members for 1995. In October, 1996, we evaluated a fruitful success in all the subjects which developed not only organic electrochemistry remarkably but also contributed to build many organic reaction systems being unable to perform by conventional organic chemistry methods. Furthermore, the results was c … More ontributed to build interdisciplinary areas with coordination chemistry and biochemistry. Its shoul be mentioned that asymmetric or enantioselective electrolysis was achieeved over our intial proposal which would become to a new tool in organic chemistry.2.Opening of Whole Members' Meeting and Open Symposia Six whole members' meetings and 5 open symposia were connectively opened as well as many times of meetings for management group and each research subject groups. It is noticed that the group leaders arranged actively to maintain informal four cooperative research systems concerning reactive metal surface electrode, electrode reaction by physical method, biofunctionality throughelectron transfer and chiral synthesis.3.Printing Meterials Research reports composed of each 2 pages in Japanese and English versions by all the members were published in the end of each years and a collective research report by 4 English pages of every member was done in December, 1996. Abstracts at the whole members' meetings and open symposia were not only distributed to the members and other participants every time, but 12 times of news letters relating the research were also distributed to the members. An English book "New Challenges in Organic Electrochemistry" which was applied a support to Monbusho is being prepared to publish in February, 1998. Less