Reactive Organometallics

为了获得未来化学转化的创新方法，本研究项目设计并生产了适合用途的活性金属化合物，重点阐明了它们的催化和分子识别功能，并探讨了它们作为功能材料的可能性。根据研究主题设立了以下研究小组：A)过渡金属的活性有机金属(S.I.Murahashi)B)非过渡金属的活性金属(R.Okazaki)C)有机活性中间体的有机金属(Y.Yamamoto)D)活性金属的催化(A.Yamamoto)E)活性金属的分子识别(Y.Moro-Oka)共110名研究人员参与了这一项目，因此，在金属有机化学、有机合成、催化、课题组组长和评价组组长会议每年召开两次(共七次)，以促进和推广该项目。举办了7次公开研讨会，让研究人员之间进行了生动而有意义的交流，包括研究人员和外部私营企业的研究人员在内的约200人参加了每次研讨会。研讨会的要旨每次都发表，并分发给有关各方。此外，我们还发布了8次公关公告，并以英文提交了我们为期三年的研究报告《活性有机金属-合成与功能》并分发给文部省和广大研究人员，使我们的成果在国内外广为人知。

Aiming to acquire innovative method of chemical transformation for the future, the present research project designed and produced reactive organometallics that suit appropriate purposes, and placed emphasis on clarifying their function of catalysis and molecular recognition and examining their possibility of working as functional materials. The following research groups were set up depending on the research theme :A) Reactive Organometallics of Transition Metals (S.-I.Murahashi)B) Reactive Organometallics of Non-transition Metals (R.Okazaki)C) Organometallics of organic Active Intermediates (Y.Yamamoto)D) Catalysis of Reactive Organometallics (A.Yamamoto)E) Molecular Recognition of Reactive Organometallics (Y.Moro-oka)110 researchers in total engaged in this project and in consequence, fruitful results that are original enough to promoto the introduction of the leading technology were obtained in the field of organometallic chemistry, organic synthesis, catalysis, and functional materials.The meetings of head of research group and evaluation group were held twice a year (seven in total) to promote and to generalize the project. Open symposiums were held 7 times to exchange lively and meaningful opinions between researchers, and about 200 people including researchers and those from private enterprises from outside took part in every symposium. The gist of the symposium was published each time and was distributed to all concerned. In addition, we issued public relations bulletins 8 times and also filed a report on our three-year research "Reactive organometallics-Synthesis and Function- " in English and distributed it to the Ministry of Education, Science, Culture and Sports, and researchers at large to make our results widely known at home as well as abroad.