Aminoimidazolin-2-imine and the 1,8-disubstituted naphthalene scaffold in the chemistry of the elements aluminium und boron

该项目涉及最近开发的氨基咪唑-2-亚胺配体类，用于硼和铝元素的络合。在此基础上，我们将合成具有B=NH母基序的亚硼烷的原型代表，并进行后续化学表征。同样的配体类也可以用于制备低价Al(I)化合物（铝烯），其化学性质将被探讨。在第二个单独的项目部分，铝和硼元素将被连接起来。1,8-二取代萘实体在电子精确Al-B键的生成中被提出，包括进一步的化学阐述。

The project deals with the recently developed ligand class of aminoimidazoline-2-imines, which are employed in the complexation of the elements boron and aluminium. Based on previous findings from our group the archetypal representatives of iminoboranes with the parent B=NH motif will be synthesized and characterized by follow-up chemistry. The same ligand class also lents itself for the preparation of low valent Al(I) compounds (alumylenes), the chemistry of which will be explored. In a second, separate project part the elements aluminium and boron will be connected. The 1,8-disubstituted napththalene entity is presented in the generation of electron precise Al-B bonds, including the elaboration of further chemistry.