Regio-controlled Functionalization of Endohedral Metallofullerene

面内金属富勒烯因其新颖的结构和电学、磁学性质而备受关注。在本研究中，我成功地通过化学反应将取代基区域选择性地引入到富勒烯碳笼上，成功地合成了新的富勒烯衍生物。通过光谱分析和单晶X射线分析，成功地对这些化合物进行了表征。本论文的研究结果将为新功能材料的合成和新功能材料的开发提供参考。

Endohedral metallofullerenes have att racted much attention because of their novel structures and electronic and magnetic properties. In this study, I succeeded in the synthesis of new derivatives of endohedral metallofullerenes by chemical reactions, in which the substituents were regioselectively introduced onto fullerene carbon cage in a high yield. I also succeeded in the characterization of these derivativesby using of spectroscopy and a single-crystal X-ray analysis. The results in this study for functionallization of endohedral metal of ullerenes will be useful for synthesis of derivatives and developing new functional materials