SOLVENT-FREE AND COMPLETE SOLID-PHASE CATALYSIS USING SOLID CATALYST・SOLID SUBSTRATE・SOLID REAGENTS

在常温常压氢气压力下，Pd/C催化剂能有效地催化各种可还原官能团的无溶剂和固相加氢反应，且不需要任何液体材料。Pd/C催化铃木？在绝对固相条件下，固体Pd/C和Cs2CO3或K2CO3存在下，固体芳基溴化物与固体芳基硼酸发生Miyaura偶联反应，生成固体联芳基。

The solvent-free and solid-phase hydrogenation of various reducible functionalities was efficiently catalyzed by heterogeneous palladium on carbon(Pd/C) under ambient hydrogen pressure and temperature without any liquid materials. The Pd/C-catalyzed Suzuki? Miyaura coupling reaction between solid arylbromides and solid arylboronic acids in the presence of solid Pd/C and Cs2CO3 or K2CO3 leading to the formation of solid biaryls has also been efficiently achieved under the absolute solid-phase conditions.