Conversion of Residual lignin generated during bioethanol production to functional materials for environment conservation
Conversion of Residual lignin generated during bioethanol production to functional materials for environment conservation
批准号:
21380109
负责人:
MATSUSHITA Yasuyuki
金额:
$11.4万
依托单位:
依托单位国家:
日本
项目类别:
Grant-in-Aid for Scientific Research (B)
财政年份:
2009
资助国家:
日本
项目状态:
已结题
起止时间:
2009 至 2011
中文摘要
为了将木质纤维素原料生产生物乙醇过程中产生的残余木质素转化为环保功能材料,进行碱水热处理,然后与丙烯酸发生共聚。然而,由于木质素与丙烯酸的相容性差,共聚反应未能成功。将木质素与ε-己内酯共聚,得到具有高溶胀性的功能性聚合物。研究了水热处理对残余木质素的增溶机理。
英文摘要
In order to convert the residual lignin generated during bioethanol production using lignocellulosic materials into functional materials for environmental conservation, hydrothermal treatment with alkali was conducted followed by co-polymerization was occurred with acrylic acid. However, the co-polymerization was not succeed because of poor compatibility between the lignin and acrylic acid. The lignin was co-polymerized withε-caprolactone to obtain the functional polymer with high swellability. The solubilization mechanism of residual lignin by hydrothermal treatment was investigated.
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水熱反応により水溶化した硫酸リグニンの構造に関する研究
水热反应溶解于水的硫酸木质素的结构研究
DOI:
--
发表时间:
2010
期刊:
影响因子:
--
作者:
[Yamada Y, Awano T, Fujita M, Takabe K, 松下泰幸]
通讯作者:
松下泰幸
Conversion of sulfuric acid lignin generated during bioethanol production from lignocelluloses materials into polyesters withε-caprolactone
用ε-己内酯将木质纤维素材料生产生物乙醇过程中产生的硫酸木质素转化为聚酯
DOI:
--
发表时间:
2011
期刊:
影响因子:
--
作者:
[Y. Matsushita, T. Inomata, Y. Takagi, T. Hasegawa, K. Fukushima]
通讯作者:
K. Fukushima
硫酸リグニンを原料にしたポリエステルの合成
以硫酸木质素为原料合成聚酯
DOI:
--
发表时间:
2009
期刊:
影响因子:
--
作者:
[T.Suzuki, T.Shinomoto, H.Mateuzaki, K.Suzuki, N.Okazaki, Y.Saito, H.Kita, H.Tamai, 松下泰幸]
通讯作者:
松下泰幸
硫酸リグニンを原料としたポリエステルの合成
以硫酸木质素为原料合成聚酯
DOI:
--
发表时间:
2010
期刊:
影响因子:
--
作者:
[松下泰幸,猪又豊生,高木康雄,長谷川達也,福島和彦]
通讯作者:
松下泰幸,猪又豊生,高木康雄,長谷川達也,福島和彦
Conversion of sulfuric acid lignin generated during bioethanol production from lignocellulosic materials into polyesters withε-caprolactone
用ε-己内酯将木质纤维素材料生产生物乙醇过程中产生的硫酸木质素转化为聚酯
DOI:
--
发表时间:
2011
期刊:
Journal of Wood Science
影响因子:
2.9
作者:
[Y. Matsushita, T. Inomata, Y. Takagi, T. Hasegawa, K. Fukushima]
通讯作者:
K. Fukushima
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A Genetic Engineering Approach which Permits Immediate Loading of Dental Implant
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依托单位:
海外基金