Control of Boron Functionality Introduction Reactions Through B-H Bond Activation and Their Applications

我们研究了金属催化的B-H化合物的交叉偶联反应，为C-X键或C-H键转化为C-B键提供了一种直接的方法。本研究介绍了几种参与芳基卤化物催化硼化反应的氢硼烷。例如，与双氮唑的反应显示出高水平的官能团相容性，由于低刘易斯酸度。此外，本研究还为我们提供了一些关于催化C-H硼化反应中区域选择性控制的有趣信息。

We investigated metal-catalyzed cross-coupling reactions of B-H compounds, which provides a direct method for conversion of C-X bonds or C-H bonds to C-B bonds. The present studies introduced several hydroboranes to participate in the catalytic borylation of aryl halides. For example, the reaction with a diazaborole showed the high level of functional group compatibility due to the low Lewis acidity. In addition, the present studies gave us some interesting information on the control of regioselectivity in the catalytic C-H borylations.