Fabrication of Highly Efficient Slid State Indicator Phase for Chemiluminescence Sensing

1.使用基础催化剂制造固体状态指示器相位（1）基本金属（镁和钡）过氧化物被处理，用氢过氧化物溶液找到了有效的化学指示器相位（CL）对发光醇和荧光素的敏感性指示器相位。它们已成功地用于对某些碳酸的后柱检测的Luminol衍生物进行了研究。而且，它还发现了用过氧化物单硫醚溶液和氢过氧化物和硝酸氧化反应介质诱导CL的混合溶液，用过氧化物和硝酸氧化反应介质诱导CL。（2）在CL传感器的不同化学品种类上存在强烈的非离子离子交换沉积物，这些化学品种类都是不流动的，被禁止的敏感性指标相位。For instance， luminol-immobilized resins were usable for a O型D22型D2 gas sensor capable of detecting O型D22型D2 gas as low as ppm levels。The Sensor was applied to determine O-D22-D2 gas in city gas and N-D22-D2 gas. 2.使用surfactant bilayerBoth bilayer - forming surfactant and manganese （II） - porphylin complex molecules were immobolized on the matrices like polymers， sol-gel silica or paraffins。他们已经测试了肾上腺素传感，并成功地应用于真正的样本。在指示器相位上识别反应性物种的CL生成仅通过添加分析解决方案，在指示器相位上制造了基本金属氧化物上的反应性物种的存在进行了有力的建议。Thus spectroscopic （ESR和RF） and chemical methods reactive species的标识。作为一种结果，羟基、超氧化物、硫代和硝基二氧化物自由基物在其表面上找到了存在，因此受到了尊重。

1. Fabrication of solid state indicator phase using base catalyst(1) Basic metal (magnesium and barium) peroxides obtained by treating their corresponding metal oxides with a hydrogen peroxide solution were found to be efficient indicator phases for chemiluminescence (CL) sensing of luminol and lucigenin. They were successfully utilized for the post-column detection of the luminol derivatives of some carbonic acids. And also it was found that the treatment of bariumoxide with a peroxomonosulfate solution and a mixed solution of hydrogen peroxide and nitrite yielded oxidative reaction media inducing CL for luminol and nucleic bases.(2) Strongly anionic ion-exchange resins on which various chemical species were immobilized exhibited sensitive indicator phases for CL sensor. For instance, luminol-immobilized resins were usable for a OィイD22ィエD2 gas sensor capable of detecting OィイD22ィエD2 gas as low as ppm levels. The sensor was applied to determine OィイD22ィエD2 gas in city gas and NィイD22ィエD2 gas.2. Fabrication of solid state indicator phase using surfactant bilayerBoth bilayer - forming surfactant and manganese (II) - porphylin complex molecules were immobolized on the matrices like polymers, sol-gel silica or paraffins. They were examined for adrenalin sensing and successfully applied to real samples.3. Identification of reactive species on the indicator phaseThe CL generation by just adding analyte solution on the indicator phase fabricated on the basic metal oxides strongly suggests the existence of reactive species on their surface. Thus spectroscopic (ESR and RF) and chemical methods were subjected to the identification of the reactive species. As results, hydroxyl, superoxide, sulfate and nitrogen dioxide radicals were found to exist on their surface, respectively.