Whodunit? Determining the source and climatic forcing of unidentified volcanic eruptions from ice core archives.

大型火山事件的影响和频率对我们的社会很重要，对全球气候，政府以及航空和农业等行业都有影响。如果火山烟流到达平流层并在全球范围内循环，则大气中火山硫酸盐气溶胶排放物的冷却效果会延长（Robock，2000年）。因此，对过去的火山活动进行准确、高分辨率的记录对于了解大型火山活动的频率和气候影响非常重要，这些火山活动可能会对我们的社会产生重大影响。我们可以从冰芯记录中更多地了解大型火山事件的规模和位置，冰芯记录可以保护硫酸盐和火山灰层免受局部和远端喷发的影响（例如：Sigl等人。因此，这种连续的高分辨率冰记录对于了解过去的火山-气候联系是非常宝贵的。该项目旨在利用火山硫酸盐矿床的硫同位素分析和冰芯记录中火山碎屑的地球化学特征，以确定最近地质历史（<20万年）大喷发的羽流高度、火山源和气候作用力。将使用柱化学和多收集器电感耦合等离子体质谱法（MC-ICP-MS）进行多种硫同位素分析。同位素特征将有助于通过是否存在质量独立分馏来确定平流层或对流层羽流高度（Baroni等人，2007年，2008年），并通过比较同位素数据和冰芯喷发记录中的SO 4浓度曲线来确定源火山的纬度（Burke等人，2019年）。来自大型未知喷发的火山灰将使用电子探针显微分析进行地球化学特征分析，提供独特的指纹，可用于确定大型喷发的潜在来源，并辅以S同位素数据提供的纬度信息。火山灰结果的解释也将有助于理解过去喷发的火山灰的分散（沃森等人，2016）。一旦使用这些技术对过去喷发的震源位置和规模进行了评估，就可以评估气候影响。这些特征对硫酸盐气溶胶在大气中的空间范围和停留时间有很强的控制作用，从而可以评估过去火山爆发对全球气候的影响。例如，2008.地球物理研究杂志，113（D20）。pp.D20112.Baroni，M.例如，2007. Science，315（5808）. pp. 84- 87. Burke，A.例如，2019.地球和行星科学快报，521。pp. 113- 119. Robock，A.，2000.地球物理学评论，38。第191 - 219页。Watson，E. J.等人，2016.地球和行星科学快报，460。pp.41-49.

The impact and frequency of large volcanic events is important to our society, with implications for global climate, governments, and industries such as aviation and agriculture. The cooling effect of volcanic sulfate aerosol emissions in the atmosphere is prolonged if the volcanic plume reaches the stratosphere and is globally circulated (Robock 2000). Therefore, having an accurate, high resolution record of past volcanism is important to understanding the frequency and climatic impact of large volcanic events which can significantly affect our society. We can understand more about the magnitude and location of large volcanic events from the ice core record, which can preserve sulfate and ash layers from local and distal eruptions (eg: Sigl et al. 2015). This continuous, high resolution ice record is therefore invaluable to the understanding past volcano-climate links. This project aims to use both sulfur isotope analysis of volcanic sulfate deposits, and geochemical characterisation of tephra shards from ice core records to determine the plume height, source volcano and climatic forcing of large eruptions from the recent geological past (<200,000 years). Multiple sulfur isotope analysis will be done using column chemistry and Multi Collector Inductively Coupled Plasma Mass Spectrometry (MC-ICP-MS). Isotopic signature will help determine stratospheric or tropospheric plume height by the presence (or absence) of a mass independent fractionation (Baroni et al. 2007, 2008), and latitude of source volcano from comparison of isotopic data and SO4 concentration curves across the ice core eruption record (Burke et al. 2019). Tephra from large unknown eruptions will be geochemically characterised using Electron Probe Micro Analysis, providing a unique fingerprint that can be used to determine potential sources for large eruptions, aided by latitudinal information given by S isotope data. Interpretation of tephra results will also aid understanding of dispersal of ash from past eruptions (Watson et al. 2016). Once source location and magnitude of past eruptions are evaluated using these techniques, the climatic impact can be assessed. These characteristics have a strong control on the spatial extent and residence time of the sulfate aerosols in the atmosphere, allowing the global climatic impact of past eruptions to be evaluated.Baroni, M. et al., 2008. Journal of Geophysical Research, 113(D20). pp.D20112.Baroni, M. et al., 2007. Science, 315 (5808). pp. 84-87.Burke, A. et al., 2019. Earth and Planetary Science Letters, 521. pp. 113-119.Robock, A., 2000. Reviews of Geophysics, 38. pp.191-219.Watson, E.J. et al., 2016. Earth and Planetary Science Letters, 460. pp.41-49.