理论预言的三维碳同素异构体T-carbon的制备及其物性的实验深入研究

由我国学者理论预言的三维碳同素异构体T-carbon具有蓬松的立方晶体结构和sp3电子杂化结构，由于其结构的特殊性，在储氢和显示方面具有理论上的优异性能，在能源和信息领域有着巨大的应用可能。我国学者在国际上也率先开展了T-carbon的实验研究，不仅给出了T-carbon在实验室条件下存在的证据，也提供了高通量制备T-carbon的技术途径。作为T-carbon高通量制备技术途径的提出者，申请人在本次申请中拟就T-carbon高通量制备中存在的动力学问题以及涉及储氢和光电显示的基本物性问题开展进一步的实验研究，探索高通量碳原子堆垛的机理，把握T-carbon的相稳定条件，确定T-carbon在储氢和光电显示役使条件下的物化性能，解决T-carbon作为新功能材料能否服役的基础材料问题。希望通过本次工作能为 “中国预言-中国证实-中国制造”这条新材料研发链条中的最后一个环节奠定基础。

Chinese scholar predicted a novel 3D carbon allotrope, named as T-carbon. Theoretically, it was considered to possess the excellent hydrogen storage capacity and the optoelectrical property due to its fluffy cubic crystal structure and sp3 hybrid electron orbit structure. Therefore, there is the great potential for T-carbon to be applied into the area of the energy and the display. It was also the Chinese scholar that proved the existence of T-carbon under the laboratory condition, and showed the approach of its high throughput preparation. As the author proposing the approach of high throughput preparation, the applicant would like to do further experimental exploration of the growth dynamic and the hydrogen storage as well as the optoelectrical display. The problems of carbon atom stacking way, phase stability and material properties under the performance condition would be focused this time. To achieve these aims, the works will involve four parts, i.e., high throughput preparation of T-carbon, atomic resolution of crystalline structure, material properties characterization, and applications in devices.