Novel thieno-[3,4-b]-pyrazine derivatives for non-doped red organic light-emitting diodes

Novel thieno-[3,4-b]-pyrazine derivatives for non-doped red organic light-emitting diodes
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用于非掺杂红色有机发光二极管的新型噻吩并-[3,4-b]-吡嗪衍生物

DOI:
10.1016/j.dyepig.2012.08.028
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发表时间:
2013-02
期刊:
影响因子:
4.5
通讯作者:
Qing Li
Qing Li
中科院分区:
材料科学2区
文献类型:
--
作者:
Jiuyan Li;Yongheng Duan;Qing Li

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Two novel red fluorescent thieno-[3,4-b]-pyrazine-cored molecules containing tetraphenylethylene as peripheral groups, T-TP and T-TP1, are designed and synthesized. Their photophysical, electrochemical and electroluminescent properties are investigated. They are characterized by large Stokes shifts of over 100 nm. The bulky peripheral groups enable these molecules to be well soluble and provide the site-isolation effect on the planar emissive core. These novel materials are used as non-doped emitting layer to fabricate organic light-emitting diodes (OLEDs) by vacuum evaporation technique. Saturated red emission is obtained with a maximum brightness of 1385 cd m−2and a luminance efficiency of 0.66 cd A−1.
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