Pechini's solution as precursor for Eu(III)-containing ZnO films

Pechini's solution as precursor for Eu(III)-containing ZnO films
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Pechini 溶液作为含 Eu(III) ZnO 薄膜的前体

DOI:
10.1016/s0022-4596(02)00178-0
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发表时间:
2003
影响因子:
3.3
通讯作者:
M. Davolos
M. Davolos
中科院分区:
化学3区
文献类型:
--
作者:
S. Lima;F. Sigoli;M. Davolos

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平板显示器(FPD)的市场和对高效彩色发光薄膜的需求一直在快速增长。在这项工作中,薄膜获得从Pechini的溶液通过浸涂。对绿色薄膜在873 K下进行热处理,得到1at%的ZnO:Eu薄膜。使用经水热处理的Schott®玻璃板作为基材。通过光学显微镜观察,膜具有马赛克形状的特征。该特征是基板热处理的结果。薄膜沉积降低了可见光范围内的基板透射率。当激发7 F0 → 5L 6(392 nm)Eu ~(3+)跃迁时,可以探测到5D 0 → 7 FJ(J=1,2,3,4)跃迁的发射。用ZnO激发波长观察到5D 0 → 7 F2跃迁,表明能量从ZnO转移到Eu ~(3+)离子。
The flat-panel-display's (FPD) market and demand for highly efficient and colored luminescent films have been growing quickly. In this work, thin films were obtained from Pechini's solution by dip-coating. The green films were thermally treated at 873K in order to get ZnO:Eu 1at% thin film. A Schott®glass plate hydrothermally treated was used as substrate. The films have a mosaic shaped feature that was observed by optical microscopy. That feature is a result of substrate thermal treatment. The film deposition decreases the substrate transmittance in the visible range. When the7F0→5L6(392nm) Eu3+transition is excited, it is possible to detect emission from5D0→7FJ(J=1, 2, 3 and 4) transitions. The5D0→7F2transition is also observed by using ZnO excitation wavelengths indicating energy transfer from ZnO to Eu3+ion.
DOI: 10.1126/science.277.5330.1242
发表时间: 1997-08-29
期刊: SCIENCE
影响因子: 56.9
作者:
Stupp, SI;Braun, PV
通讯作者: Braun, PV