Simple reaction to prepare a heat-resistant and insensitive explosive (2-nitro-[1,2,4]triazolo[1,5-a][1,3,5]triazine-5,7-diamine) and its derivatives
Simple reaction to prepare a heat-resistant and insensitive explosive (2-nitro-[1,2,4]triazolo[1,5-a][1,3,5]triazine-5,7-diamine) and its derivatives
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简单反应制备耐热钝感炸药（2-硝基-[1,2,4]三唑并[1,5-a][1,3,5]三嗪-5,7-二胺）及其衍生物
DOI：
10.1016/j.cej.2021.134297
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发表时间：
2021-12
影响因子：
15.1
通讯作者：
Wenquan Zhang
中科院分区：
文献类型：
--
作者：
Yuteng Cao;Ziwu Cai;Honglei Xia;Kangcai Wang;Yu Liu;Qinghua Zhang;Wenquan Zhang
低成本、高产率、安全性好、合成工艺简单是含能化合物工程制备中必须解决的问题，甚至在一定程度上超出了对高能级的追求。本工作设计并合成了一种新型的5，6-稠合含能分子2-硝基-[1，2，4]三唑并[1，5-a][1，3，5]三嗪-5，7-二胺(NTTD)。通过引入氧化剂(HNO3和HClO4)和高能基团(-NHNO2)制备了NTTD的衍生物，其中一些具有良好的综合性能。重要的是，NTTD具有优异的热稳定性和低机械感度。整个制备过程具有操作简单、时间短、试剂廉价简单、重复性好、产率高等优点，有利于大规模制备，表明NTTD有望成为耐热钝感炸药的潜在候选材料。
Low cost, high yield, good safety, and simple synthesis process are the problems that must be solved in the engineering preparation of energetic compounds, even beyond the pursuit of high energy level to some extent. In this work, a novel 5,6-fused energetic molecule 2-nitro-[1,2,4]triazolo[1,5-a][1,3,5] triazine-5,7-diamine (NTTD) was designed and easily obtained. By the introduction of oxidants (HNO3and HClO4) and high-energy groups (–NHNO2), the derivatives of NTTD were prepared, some of which exhibited good comprehensive properties. Importantly, NTTD features excellent thermostability and low mechanical sensitivities. The whole preparation process has advantages of simple operation, short time, cheap and simple reagents, good repeatability, and high yield, which are conducive to large-scale preparation, indicating that NTTD can be a potential candidate of heat-resistant and insensitive explosives.
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影响因子：
15
作者：
Hu, Lu;Yin, Ping;Shreeve, Jean'ne M.
通讯作者：
Shreeve, Jean'ne M.
影响因子：
2.8
作者：
M. S. Klenov;O. V. Anikin;A. M. Churakov;Y. Strelenko;I. Fedyanin;I. Ananyev;V. Tartakovsky
通讯作者：
M. S. Klenov;O. V. Anikin;A. M. Churakov;Y. Strelenko;I. Fedyanin;I. Ananyev;V. Tartakovsky
影响因子：
2.4
作者：
Chavez, DE;Hiskey, MA
通讯作者：
Hiskey, MA
影响因子：
4
作者：
Jinchao Ma;G. Cheng;X. Ju;Zhen-xin Yi;Shun-guan Zhu;Zaichao Zhang;Hongwei Yang
通讯作者：
Jinchao Ma;G. Cheng;X. Ju;Zhen-xin Yi;Shun-guan Zhu;Zaichao Zhang;Hongwei Yang
DOI：
10.1002/slct.201800005
发表时间：
2018-05
期刊：
--
影响因子：
--
作者：
Baojing Zhao;Piaopiao Wang;W. Fu;Chuanqiang Li;Zhiming Zhou
通讯作者：
Baojing Zhao;Piaopiao Wang;W. Fu;Chuanqiang Li;Zhiming Zhou