Examination of Spontaneous Orientation Polarization in Wet‐Processed Tris(8‐hydroxyquinolinato)aluminum Film Measured by Rotary Kelvin Probe Method

Examination of Spontaneous Orientation Polarization in Wet‐Processed Tris(8‐hydroxyquinolinato)aluminum Film Measured by Rotary Kelvin Probe Method
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用旋转开尔文探针法测量湿法加工的三(8-羟基喹啉)铝膜的自发取向偏振

DOI:
10.1002/pssa.202000790
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发表时间:
2021
期刊:
physica status solidi (a)
影响因子:
--
通讯作者:
Ishii Hisao
Ishii Hisao
中科院分区:
--
文献类型:
--
作者:
Ohara Masahiro;Watanabe Tatsuya;Tanaka Yuya;Ishii Hisao

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近年来,自发取向极化(SOP)作为提高有机发光器件性能的重要因素引起了广泛关注。然而,到目前为止,SOP仅针对通过真空气相沉积制造的薄膜进行了报道,并且没有直接尝试检查湿法加工薄膜的SOP的存在。为了检查这种现象,有必要完全排除样品系统中的光照射,因为光载流子可以减少或消除由SOP形成引起的表面电势。在此,使用新型旋转开尔文探针法研究了在氧化铟锡基底上湿法处理的三(8-羟基喹啉)铝(Alq 3)膜的SOP。在全暗条件下进行成膜和表面电位测量。对于1 μm厚的Alq 3膜,观察到−0.33 V的表面电位漂移,表明与真空蒸发膜相比,湿法处理的Alq 3膜的SOP可以忽略不计。
Recently, a spontaneous orientation polarization (SOP) has attracted much attention as an important factor improving the performance of organic light‐emitting devices. However, so far, SOP is reported only for films fabricated by vacuum vapor deposition, and no direct attempt is made to examine the existence of SOP for wet‐processed film. To examine this phenomenon, it is necessary to completely exclude light illumination in the sample system, as photocarriers can reduce or eliminate the surface potential caused by the SOP formation. Herein, the SOP of wet‐processed tris(8‐hydroxyquinolinato)aluminum (Alq3) film on an indium‐tin‐oxide substrate is investigated using a novel rotary Kelvin probe method. Film formation and surface potential measurement are conducted under completely dark condition. A surface potential shift of −0.33 V is observed for a 1 μm thick film of Alq3, indicating that the SOP of wet‐processed Alq3film is negligible, in contrast to vacuum‐evaporated film.
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