Conjugated polyelectrolyte brushes with extremely high charge density for improved energy transfer and fluorescence quenching applications
Conjugated polyelectrolyte brushes with extremely high charge density for improved energy transfer and fluorescence quenching applications
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具有极高电荷密度的共轭聚电解质刷，可改善能量转移和荧光猝灭应用
DOI：
10.1039/c1py00213a
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发表时间：
2011-09
影响因子：
4.6
通讯作者：
Lu Xiaomei
中科院分区：
文献类型：
--
作者：
Huang Wei;Fan Quli;Zhang Zhiyong;Lu Xiaomei
A conjugated polyelectrolyte brush (PB3) composed of a polyfluorene backbone and poly[2-(dimethylamino)ethyl methacrylate] (PDMAEMA) side chains is synthesized via atom transfer radical polymerization (ATRP), and its properties are investigated and compared with its linear counterpart (P2, poly[9,9′-bis(6-N,N,N-trimethylammoniumhexyl)fluorene] dibromide). Despite the same conjugated backbones for PB3 and P2, the polymer brush architecture of PB3 endows it with an extremely high charge density, consequently give rise to better optical stability, higher water solubility (28 mg mL−1) and higher quantum efficiency (52%) as compared to those of P2; moreover, it induces stronger electrostatic attraction with oppositely-charged analytes, making PB3 contact the energy donor or quencher molecules much more efficiently than P2 does. As such, PB3 can afford not only higher FRET-amplified dye emission but also larger fluorescence quenching constant as compared to P2. With its high water-solubility, the fluorescence of PB3 sustains in the presence of a large amount of ssDNA, showing its optical durability in complicated biological media. As a result, CPE brushes could constitute a new generation of water-soluble fluorescent macromolecules having desirable optical and biochemical properties for various sensing applications.
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DOI：
10.1002/pola.22129
发表时间：
2007-08
期刊：
Journal of Polymer Science Part A
影响因子：
--
作者：
Kanyi Pu;Yi Chen;Xiaoying Qi;Chun-Yang Qin;Qing-Quan Chen;Hongyu Wang;Yun Deng;Quli Fan;Yan-Qin Huang;Shu-juan Liu;Wei Wei-Wei;Bo Peng;Wei Huang
通讯作者：
Kanyi Pu;Yi Chen;Xiaoying Qi;Chun-Yang Qin;Qing-Quan Chen;Hongyu Wang;Yun Deng;Quli Fan;Yan-Qin Huang;Shu-juan Liu;Wei Wei-Wei;Bo Peng;Wei Huang
影响因子：
4.9
作者：
Kan‐Yi Pu;Ruoyu Zhan;B. Liu
通讯作者：
Kan‐Yi Pu;Ruoyu Zhan;B. Liu
影响因子：
5.5
作者：
S. Lu;Quli Fan;S. Chua;Wei Huang
通讯作者：
S. Lu;Quli Fan;S. Chua;Wei Huang
影响因子：
15
作者：
Howes, Philip;Green, Mark;Hughes, Mary
通讯作者：
Hughes, Mary
影响因子：
15
作者：
He, F;Tang, YL;Zhu, DB
通讯作者：
Zhu, DB