Profiling sulfonate ester stability: identification of complementary protecting groups for sulfonates.
Profiling sulfonate ester stability: identification of complementary protecting groups for sulfonates.
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DOI：
10.1021/jo1007338
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发表时间：
2010-07-02
影响因子：
3.6
通讯作者：
Miller, Stephen C.
中科院分区：
文献类型：
--
作者：
Miller, Stephen C.
Sulfonation is prized for its ability to impart water-solubility to hydrophobic molecules such as dyes. This modification is usually performed as a final step, since sulfonated molecules are poorly soluble in most organic solvents, which complicates their synthesis and purification. This work compares the intrinsic lability of different sulfonate esters, identifying new sulfonate protecting groups and mild, selective cleavage conditions.
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