Vibrational Spectroscopic Techniques for Probing Bioelectrochemical Systems.
Vibrational Spectroscopic Techniques for Probing Bioelectrochemical Systems.
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用于探测生物电化学系统的振动光谱技术。
DOI:
10.1007/10_2016_3
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发表时间:
2016
期刊:
影响因子:
--
通讯作者:
Ash PA
中科院分区:
文献类型:
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作者:
Ash PA
A more complete understanding of bioelectrochemical interfaces is of increasing importance in both fundamental studies and biotechnological applications of proteins. Bioelectrochemical methods provide detailed information about the activity or rate of a process, but in situ spectroscopic methods are needed to gain direct structural insight into functionally relevant states. A number of methods have been reported that allow electrochemical and spectroscopic data to be collected from the same electrode, providing direct spectroscopic ‘snapshots’ of protein function, and here we focus on the application of infrared and Raman spectroscopies to the study of electrode-immobilised species. The ability to probe coordination at metal centres, protonation changes in amino acid side chains, reaction-induced changes in organic cofactors or substrates, protein orientation and subtle changes in protein secondary structure simultaneously, rapidly and at room temperature means that vibrational spectroscopic approaches are almost uniquely applicable to answering a wide range of questions in bioelectrochemistry.
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DOI:
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发表时间:
2015
期刊:
影响因子:
--
作者:
D. Millo;H. K. Ly
通讯作者:
H. K. Ly
DOI:
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发表时间:
2007
期刊:
影响因子:
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作者:
I. Suzuki;A. Yamauchi;Y. Sakashita;K. Hirose;T. Miura;T. Hayashita;M. Osawa;M. Osawa;M. Osawa
通讯作者:
M. Osawa
DOI:
10.1039/c5cp00023h
发表时间:
2015
期刊:
Physical chemistry chemical physics : PCCP
影响因子:
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作者:
C. Renault;L. Nicole;C. Sanchez;C. Costentin;V. Balland;B. Limoges
通讯作者:
B. Limoges
影响因子:
15.1
作者:
R. Aroca;S. Rodriguez-Llorente
通讯作者:
R. Aroca;S. Rodriguez-Llorente
影响因子:
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作者:
Óscar Gutiérrez‐Sanz;O. Rüdiger;A. L. De Lacey
通讯作者:
A. L. De Lacey