Crystallization Kinetics and Hydrophilicity Improvement of Biodegradable Poly(butylene succinate) in its Miscible Blends with Poly(ethylene oxide)

Crystallization Kinetics and Hydrophilicity Improvement of Biodegradable Poly(butylene succinate) in its Miscible Blends with Poly(ethylene oxide)
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可生物降解聚丁二酸丁二醇酯与聚环氧乙烷混溶共混物的结晶动力学和亲水性改进

DOI:
10.1002/mame.200800192
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发表时间:
2008-11
影响因子:
3.9
通讯作者:
Yang W
Yang W
中科院分区:
材料科学3区
文献类型:
--
作者:
Qiu Z;Lu J;Yang W

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The spherulitic morphology and growth, overall isothermal crystallization kinetics and hydrophilicity of PBSU were investigated by POM, DSC and WCA measurements in its miscible blends with PEO. The Hoffman-Lauritzen equation was employed to analyze the spherulitic growth rates of neat and blended PBSU, which show a crystallization regime transition between regime II and III. The overall crystallization rates of PBSU decreased with increasing crystallization temperature, regardless of blend composition, while the crystallization mechanism does not change. A significant improvement in the hydrophilicity of PBSU can be achieved by blending with different weight fractions of PEO, which may be essential for the practical application of PBSU/PEO blends.
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