High thermal shock resistance realized by Ti/TiH2 doped tungsten-potassium alloys

High thermal shock resistance realized by Ti/TiH2 doped tungsten-potassium alloys
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Ti/TiH2 掺杂钨钾合金实现高抗热震性

DOI:
10.1016/j.jallcom.2018.11.389
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发表时间:
2019-04
影响因子:
6.2
通讯作者:
Jun Tang
Jun Tang
中科院分区:
材料科学2区
文献类型:
--
作者:
Longqing Chen;Bo Huang;Xiaoliang Yang;Youyun Lian;Xiang Liu;Jun Tang

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Tungsten-potassium-titanium (W-K-Ti) alloys were fabricated by spark-plasma-sintering (SPS) and traditional rotary swaging (RS) techniques. Doping conditions and sintering methods were compared on the relative density, microstructure, hardness, recrystallization temperature, and the thermal shock resistance properties. Transient heat loads under 0.37 GW m−2were applied on the W-K-Ti samples at room temperature for different cycles and pulsed durations. It was found that moderate Ti-doping (0.05 and 0.075 wt%) in W-K alloys can enhance the thermal shock resistance. Low-cycle thermal fatigue test suggested better thermal shock resistance in SPS-sintered W-K-Ti alloy (SPS-W-K-Ti) using TiH2dopant. The main reason was that the decomposition of TiH2significantly reduced the oxygen content of the ingots, which improved the ductility and thermal shock resistance of tungsten alloys. Further fracture analyses indicated that Ti-doping through TiH2formed intra- and inter- Ti-rich voids in TiH2-doped W-K alloy, while only intergranular Ti particles were found lying along grain boundaries in the Ti-doped one. The formation mechanism of the Ti-rich voids was investigated in detail. This work provides a potential route for obtaining plasma facing materials with high thermal shock resistance.
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