Highly reliable photosensitive organic-inorganic hybrid passivation layers for a-InGaZnO thin-film transistors

Highly reliable photosensitive organic-inorganic hybrid passivation layers for a-InGaZnO thin-film transistors
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用于a-InGaZnO薄膜晶体管的高可靠性光敏有机-无机混合钝化层

DOI:
10.1063/1.4927274
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发表时间:
2015
影响因子:
4
通讯作者:
Y. Uraoka
Y. Uraoka
中科院分区:
物理与天体物理2区
文献类型:
--
作者:
J. Bermundo;Y. Ishikawa;H. Yamazaki;T. Nonaka;M. Fujii;Y. Uraoka

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报道了一种在非晶态InGaZnO(a-IGZO)薄膜晶体管(TFT)上制备的光敏混合钝化材料,大大提高了其稳定性,改善了其电学特性。基于聚倍半硅氧烷的混合钝化是透明的,并使用简单的溶液工艺制备。由于钝化是光敏的,所以在TFT制造过程中从未进行过干法刻蚀。用该材料钝化的TFT在正偏压下的阈值电压漂移为0.5 V,在负偏压下的阈值电压漂移为0.5 V,在负偏压下的阈值电压漂移为2.5−V。此外,经该钝化层钝化的TFT在经历高相对湿度应力后仍保持稳定,从而证实了钝化具有良好的阻挡能力。二次离子质谱分析表明,在通道区域可以发现大量的氢、碳和氟。结果表明,氢和氟都减少了氧空位,而氟对氧空位的影响较小。
We report the fabrication of a photosensitive hybrid passivation material on amorphous InGaZnO (a-IGZO) thin-film transistors (TFTs) that greatly enhance its stability and improve its electrical characteristics. The hybrid passivation based on polysilsesquioxane is transparent and fabricated using a simple solution process. Because the passivation is photosensitive, dry etching was never performed during TFT fabrication. TFTs passivated with this material had a small threshold voltage shift of 0.5 V during positive bias stress, 0.5 V during negative bias stress, and −2.5 V during negative bias illumination stress. Furthermore, TFTs passivated by this layer were stable after being subjected to high relative humidity stress — confirming the superb barrier ability of the passivation. Analysis of secondary ion mass spectrometry showed that a large amount of hydrogen, carbon, and fluorine can be found in the channel region. We show that both hydrogen and fluorine reduced oxygen vacancies and that fluorine stab...
DOI: 10.1038/nature03090
发表时间: 2004-11-25
期刊: NATURE
影响因子: 64.8
作者:
Nomura, K;Ohta, H;Hosono, H
通讯作者: Hosono, H