Metal Associations in Marcellus Shale and Fate of Synthetic Hydraulic Fracturing Fluids Reacted at High Pressure and Temperature

Metal Associations in Marcellus Shale and Fate of Synthetic Hydraulic Fracturing Fluids Reacted at High Pressure and Temperature
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马塞勒斯页岩中的金属组合和高压高温下反应的合成水力压裂液的命运

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发表时间:
2016
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影响因子:
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通讯作者:
D. BurgosWilliam
D. BurgosWilliam
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作者:
L. TaskerTravis;K. PiotrowskiPaulina;L. DormanFrank;D. BurgosWilliam

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摘要非常规威尔斯气井的返排液和采出沃茨的化学性质受注入的增产液与目标地层之间的反应控制。盐和金属从地层中的释放是有据可查的,然而,有机添加剂在井下条件下的命运却没有。马塞勒斯页岩的一个露头和六个岩心样品从宾夕法尼亚州各地获得,并按顺序提取,以确定各种矿物基质中的金属协会。不同基质中的金属浓度在所分析的页岩样品中变化显著。与岩心样品相比,页岩露头中检测到的金属和盐浓度较低,这可能是由于氧化风化过程中碳酸盐和盐的溶解。页岩露头与高或低有机含量的合成水力压裂液(SFF)反应,以研究有机添加剂的命运及其对金属活化的影响。The Organic Co…
Abstract Chemistry of flowback and produced waters from unconventional gas wells is controlled by reactions between fluids injected for well stimulation and the target geologic formation. Release of salts and metals from the formations are well documented, however, the fate of organic additives under down-hole conditions is not. One outcrop and six core samples of Marcellus Shale were obtained from locations throughout Pennsylvania and sequentially extracted to determine metal associations within various mineral matrices. Metal concentrations in different matrices varied significantly across the shale samples analyzed. In comparison to core samples, lower metal and salt concentrations were detected in the shale outcrop likely due to carbonate and salt dissolution during oxidative weathering processes. The shale outcrop was reacted with synthetic hydraulic fracturing fluids (SFFs) of high or low organic content to study the fate of organic additives and their influence on metal mobilization. The organic co...
DOI: 10.1007/s10532-015-9733-6
发表时间: 2015-07-01
期刊: BIODEGRADATION
影响因子: 3.6
作者:
Kekacs, Daniel;Drollette, Brian D.;Mouser, Paula J.
通讯作者: Mouser, Paula J.