Gelatin tailored pore structure and mechanical properties of freeze-cast porous boron carbide ceramics

Gelatin tailored pore structure and mechanical properties of freeze-cast porous boron carbide ceramics
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冻铸多孔碳化硼陶瓷的明胶定制孔结构和力学性能

DOI:
10.1016/j.ceramint.2020.09.111
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发表时间:
2021
影响因子:
5.2
通讯作者:
Wen Wang
Wen Wang
中科院分区:
材料科学1区
文献类型:
--
作者:
Yang Wang;Qiang Liu;Biao Zhang;Haoqian Zhang;Yicheng Jin;Zhaoxin Zhong;Feng Ye;Wen Wang

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The architectures of porous B4C scaffolds play a pivotal role in the performance of their infiltrated composites for multiple applications. Here, we use gelation-freeze-drying approach to creating the porous B4C scaffolds with oriented channels, which are promising and relatively untested freeze-cast constructs. Addition of gelatin alters not only the porosity and shrinkage but also the pore size and morphology of the scaffolds. Specifically, as gelatin contents increase from 0 to 5 wt%, the porosity, closed porosity, and volume shrinkage range from 74.53 to 73.27%, 0.28–0.65% and 1.95–3.96%, respectively; the increased wavelength and lamellar thickness can be attributed to the enhancement in viscosity. Importantly, raised gelatin contents lead to the reduced pore aspect ratio triggering the transformation from lamellae with a high aspect ratio to ellipse shaped morphologies that contribute to the improved compressive strength ranging from 0.7 to 4.4 MPa. The freeze-cast B4C scaffolds with tailored performance by varying gelatin contents widen the application scopes of bioinspired composites.
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发表时间: 2010-03-17
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