Solubility and activity of a phosphinosulfonate palladium catalyst in water with different surfactants

Solubility and activity of a phosphinosulfonate palladium catalyst in water with different surfactants
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不同表面活性剂下膦磺酸钯催化剂在水中的溶解度和活性

DOI:
10.1039/c9py00154a
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发表时间:
2019
期刊:
影响因子:
4.6
通讯作者:
Guironnet, Damien
Guironnet, Damien
中科院分区:
化学2区
文献类型:
--
作者:
Boucher-Jacobs, Camille;Li, Bo;Schroeder, Charles M.;Guironnet, Damien

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通过表面活性剂与金属中心的配位反应,合成了水溶性膦磺酸钯配合物。考察了相应催化剂的乙烯聚合活性。表面活性剂和溶液的pH值被证明会影响活性。磷酸化的表面活性剂导致聚合具有最高的活性和稳定性。
Water-soluble phosphinosulfonate palladium complexes were synthesized by coordination of a surfactant to the metal center. The ethylene polymerization activity of the corresponding catalyst was probed. The surfactant and pH of the solution are shown to influence the activity. A phosphated surfactant resulted in polymerization with the highest activity and stability.
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