Structure and Performance Evolution of Perovskite Solar Cells under Extreme Temperatures
Structure and Performance Evolution of Perovskite Solar Cells under Extreme Temperatures
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极端温度下钙钛矿太阳能电池的结构和性能演变
DOI：
10.1002/aenm.202202887
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发表时间：
2022-10
影响因子：
27.8
通讯作者：
Antonio Abate
中科院分区：
文献类型：
--
作者：
Guixiang Li;Zhenhuang Su;Meng Li;Harrison Ka Hin Lee;Ram Datt;Declan Hughes;Chenyue Wang;Marion Flatken;Hans Köbler;José Juan Jerónimo-Rendon;Rajarshi Roy;Feng Yang;Jorge Pascual;Zhe Li;Wing Chung Tsoi;Xingyu Gao;Zhaokui Wang;Michael Saliba;Antonio Abate
金属卤化物钙钛矿太阳能电池可用于极端温度下的应用，例如在外星条件下经历的那些。然而，在极端温度下的器件性能研究很少。这项工作系统地探索了钙钛矿太阳能电池在−160和150 °C之间的性能。原位掠入射广角X射线散射揭示了钙钛矿相变和晶体无序是温度相关器件效率恶化的主要因素。结果表明，钙钛矿晶格应变和弛豫起源于极端的温度变化是可恢复的，所以是钙钛矿结构和光伏性能。这项工作提供了对极端温度下功能的深入了解，澄清了需要克服的瓶颈以及外星应用的潜力。
Metal halide perovskite solar cells may work for application in extreme temperatures, such as those experienced under extraterrestrial conditions. However, device performances in extreme temperatures are poorly investigated. This work systematically explores the performance of perovskite solar cells between −160 and 150 °C. In situ grazing‐incidence wide‐angle X‐ray scattering discloses perovskite phase transition and crystal disordering as dominant factors for the temperature‐dependent device efficiency deterioration. It is shown that perovskite lattice strain and relaxation originating from extreme temperature variations are recoverable, and so are the perovskite structure and photovoltaic performances. This work provides insights into the functioning under extreme temperatures, clarifying bottlenecks to overcome and the potential for extraterrestrial applications.
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影响因子：
16.6
作者：
Tan H;Che F;Wei M;Zhao Y;Saidaminov MI;Todorović P;Broberg D;Walters G;Tan F;Zhuang T;Sun B;Liang Z;Yuan H;Fron E;Kim J;Yang Z;Voznyy O;Asta M;Sargent EH
通讯作者：
Sargent EH
影响因子：
29.4
作者：
Chenzhe Xu;Xiwen Chen;Shokrgozar Ma;Mingyue Shi;Suicai Zhang;Zhaozhao Xiong;Wenqiang Fan;Haonan Si;Hualin Wu;Zheng Zhang;Qingliang Liao;Wanjian Yin;Z. Kang;Yue Zhang
通讯作者：
Chenzhe Xu;Xiwen Chen;Shokrgozar Ma;Mingyue Shi;Suicai Zhang;Zhaozhao Xiong;Wenqiang Fan;Haonan Si;Hualin Wu;Zheng Zhang;Qingliang Liao;Wanjian Yin;Z. Kang;Yue Zhang
影响因子：
27.8
作者：
A. Ullah;Keun Hyeong Park;H. D. Nguyen;Y. Siddique;S. F. Shah;Huyen Tran;Sunghyeok Park;Seok In Lee;Kyung‐Koo Lee;C. Han;Kihwan Kim;SeJin Ahn;Inyoung Jeong;Y. S. Park;Sungjun Hong
通讯作者：
A. Ullah;Keun Hyeong Park;H. D. Nguyen;Y. Siddique;S. F. Shah;Huyen Tran;Sunghyeok Park;Seok In Lee;Kyung‐Koo Lee;C. Han;Kihwan Kim;SeJin Ahn;Inyoung Jeong;Y. S. Park;Sungjun Hong
影响因子：
30.7
作者：
Gernaat, David E. H. J.;de Boer, Harmen Sytze;van Vuuren, Detlef P.
通讯作者：
van Vuuren, Detlef P.
影响因子：
15
作者：
Kojima, Akihiro;Teshima, Kenjiro;Miyasaka, Tsutomu
通讯作者：
Miyasaka, Tsutomu