Synthesis of N-Azaaryl Anilines: An Efficient Protocol via Smiles Rearrangement
Synthesis of N-Azaaryl Anilines: An Efficient Protocol via Smiles Rearrangement
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N-氮杂芳基苯胺的合成：通过 Smiles 重排的有效方案
DOI：
10.5012/bkcs.2013.34.2.394
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发表时间：
2013-02
影响因子：
1.7
通讯作者：
He, Xiao-Yan
中科院分区：
文献类型：
--
作者：
Shin, Dong-Soo;Wang, Li-Ying;Sun, Heng-Zhi;Yue, Huan;Wang, Xiu-Hua;Tan, Jia-Lian;Wang, Yin;Hou, Di;He, Xiao-Yan
E-mail: dsshin@changwon.ac.kr Received September 8, 2012, Accepted November 8, 2012An efficient process for the synthesis of N-azaaryl anilines via Smiles rearrangement as a tool. A variety of N-azaaryl anilines were generated by the reaction of substituted phenols, substituted anilines, aminopyridines andchloroacetyl chloride or pyridols, under base condition in good to excellent yields.Key Words : Smiles rearrangement, N-Azaaryl anilines, Amine, Phenol, SynthesisIntroductionThe pyridine ring system appears to be indispensable inthe structures of various natural products, pharmaceuticalcompounds, and other commercial substances. With pyri-dine ring in the structures, N-azaaryl anilines have attractedconsiderable attention owing to their wide range of bio-logical activities, such as antimicrobial,
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影响因子：
2.1
作者：
Zhong-Lin Xu;Hong‐Xi Li;Zhi‐Gang Ren;Wei Du;Wei-Chang Xu;J. Lang
通讯作者：
Zhong-Lin Xu;Hong‐Xi Li;Zhi‐Gang Ren;Wei Du;Wei-Chang Xu;J. Lang
影响因子：
3.6
作者：
Seechurn, Carin C. C. Johansson;Parisel, Sebastien L.;Colacot, Thomas J.
通讯作者：
Colacot, Thomas J.
影响因子：
8.4
作者：
Maiti D;Fors BP;Henderson JL;Nakamura Y;Buchwald SL
通讯作者：
Buchwald SL
影响因子：
5.2
作者：
Chen, Jinlei;Song, Guoyong;Li, Xingwei
通讯作者：
Li, Xingwei
影响因子：
1.7
作者：
Aiying Du;Shang Li Zhang;J. Miao;Baoxiang Zhao
通讯作者：
Aiying Du;Shang Li Zhang;J. Miao;Baoxiang Zhao