Modification of poly(propylene carbonate) with chain extender ADR-4368 to improve its thermal, barrier, and mechanical properties

Modification of poly(propylene carbonate) with chain extender ADR-4368 to improve its thermal, barrier, and mechanical properties
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使用扩链剂 ADR-4368 对聚碳酸丙烯酯进行改性,以提高其热性能、阻隔性能和机械性能

DOI:
10.1016/j.polymertesting.2016.07.024
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发表时间:
2016-09
期刊:
影响因子:
5.1
通讯作者:
Wang Yu-zhong
Wang Yu-zhong
中科院分区:
材料科学2区
文献类型:
--
作者:
Wang Xi-yuan;Weng Yun-xuan;Wang Wen;Huang Zhi-gang;Wang Yu-zhong

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Melt blending with the application of epoxy compound ADR-4368 as a chain extender was used to chemically modify polypropylene carbonate (PPC).1H nuclear magnetic resonance spectroscopy (1H NMR), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), and tests using a universal material testing machine, a gas permeability tester, a water vapor permeability tester and other instruments were used to assess changes in the chemical structure, thermal and mechanical properties, and barrier efficacy of PPC before and after modification.The epoxy group in ADR-4368 reacted with the terminal hydroxyl group in PPC, considerably enhancing its mechanical properties, thermal stability and barrier efficacy to O2and CO2. With the addition of 1% ADR-4368, the glass transition temperature of PPC was increased from 17 °C to 26.9 °C, while the thermal decomposition temperature (T−5%) of PPC was increased from 177.3 °C to 240.6 °C. Moreover, the tensile strength of the modified PPC was improved from 3.3 MPa to 20.7 MPa.
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