Direct light-induced (co-)grafting of photoactive polymers to graphitic nanodiamonds

Direct light-induced (co-)grafting of photoactive polymers to graphitic nanodiamonds
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光敏聚合物直接光诱导(共)接枝到石墨纳米金刚石上

DOI:
10.1039/c6py02035f
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发表时间:
2017
期刊:
影响因子:
4.6
通讯作者:
Barner-Kowollik
Barner-Kowollik
中科院分区:
化学2区
文献类型:
--
作者:
K. N. R;Trouillet;Köppe;Roesky;Goldmann;Stenzel;Barner-Kowollik

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我们介绍了直接光驱动的均接枝和共接枝的各种功能聚合物的石墨纳米金刚石(grND)产生的爆轰纳米金刚石(ND)的热退火通过光诱导的光烯醇反应,在只有两个后续的反应步骤。例如,聚(五氟苯乙烯)和聚(N-异丙基丙烯酰胺)同时共接枝到ND在一个快速,方便,无催化剂和模块化的方式。
We introduce the direct light-driven homo-grafting and co-grafting of various functional polymers to graphitic nanodiamonds (grNDs) generated by thermal annealing of detonation nanodiamonds (NDs) via the light-induced photo-enol reaction in only two subsequent reaction steps. For instance, poly(pentafluorostyrene) and poly(N-isopropylacrylamide) were simultaneously co-grafted to NDs in a rapid, facile, catalyst free and modular fashion.
Bingel-Hirsch 条件下纳米金刚石的表面改性
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期刊: Chemphyschem : a European journal of chemical physics and physical chemistry
影响因子: --
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