Mononuclear copper complex-catalyzed four-electron reduction of oxygen.
Mononuclear copper complex-catalyzed four-electron reduction of oxygen.
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DOI:
10.1021/ja100538x
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发表时间:
2010-05-26
影响因子:
15
通讯作者:
Karlin KD
中科院分区:
文献类型:
--
作者:
Fukuzumi S;Kotani H;Lucas HR;Doi K;Suenobu T;Peterson RL;Karlin KD
A mononuclear CuII complex acts as an efficient catalyst for four-electron reduction of O2 to H2O by a ferrocene derivative via formation of the dinuclear CuII peroxo complex that is further reduced in the presence of protons by a ferrocene derivative to regenerate the CuII complex.
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