Structural construction and photoluminescence tuning via energy transfer in apatite-type solid-state phosphors

Structural construction and photoluminescence tuning via energy transfer in apatite-type solid-state phosphors
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通过磷灰石型固态磷光体中的能量转移进行结构构建和光致发光调节

DOI:
10.1039/c8tc01043a
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发表时间:
2018-04
影响因子:
6.4
通讯作者:
夏志国
夏志国
中科院分区:
材料科学2区
文献类型:
--
作者:
Jun Zhou;Quanlin Liu;夏志国

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磷灰石型固态磷光体由于其在柔性晶体结构中的多功能化学组成以及用于单掺杂或共掺杂激活剂的不同晶体学位点而受到相当大的关注。由于这些原因,这些磷光体材料已经在不同领域中展示了潜在的应用,包括固态照明和显示工业。本文综述了近年来在磷灰石类荧光粉的结构设计和光致发光调控方面的研究进展。首先,我们总结了晶体化学的设计原则和典型的磷灰石型荧光粉的发现,这些荧光粉也可以由这样的矿物模型形成多种多组分磷灰石相化合物。其次,介绍了不同掺杂离子对的多色磷灰石型荧光粉及其相应的能量转移过程,从而实现荧光粉的颜色调谐,甚至实现单组分白色发光。因此,这篇综述将促进新的磷灰石型荧光粉的发现和光致发光的调控策略,通过共掺杂激活剂和相关的ET行为的研究。
Apatite-type solid-state phosphors have received considerable attention for their versatile chemical compositions in flexible crystal structures as well as the different crystallographic sites for the single doped or codoped activators. For these reasons, these phosphor materials have demonstrated potential applications in different fields, including the solid-state lighting and display industry. Herein, the recent developments in the structural design and photoluminescence tuning of the apatite-type phosphors have been reviewed. First, we summarized the design principles of the crystal chemistry and the discovery of typical apatite-type phosphors, which can also form a variety of multi-component apatite phase compounds from such a mineral model. Second, we described the development of multi-color apatite-type phosphors originating from different doping ion couples and their corresponding energy transfer (ET) process, which in turn can tune the emission colors of phosphors and even realize the single-component white light-emitting emission. Accordingly, this review will promote research on the discovery of new apatite-type phosphors and the photoluminescence tuning strategy via the codoped activators and the related ET behaviour.
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