Fabrication of metal nanocluster and nanoparticles in the CaO-Bi2O3-B2O3-Al2O3-TiO2 glass by irradiation of XeCl pulsed laser.

Fabrication of metal nanocluster and nanoparticles in the CaO-Bi2O3-B2O3-Al2O3-TiO2 glass by irradiation of XeCl pulsed laser.
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通过 XeCl 脉冲激光照射在 CaO-Bi2O3-B2O3-Al2O3-TiO2 玻璃中制备金属纳米簇和纳米颗粒。

DOI:
10.1364/oe.16.002614
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发表时间:
2008
期刊:
影响因子:
3.8
通讯作者:
T. Komatsu
T. Komatsu
中科院分区:
物理与天体物理2区
文献类型:
--
作者:
H. Masai;S. Mizuno;T. Fujiwara;H. Mori;T. Komatsu

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我们报道了用XeCl激光在CaO-Bi(2)O(3)-B(2)O(3)-Al(2)O(3)-TiO 2玻璃表面制备含有金属纳米团簇的纳米颗粒。我们已经证明,表面形态,如含有纳米颗粒或光滑的平面,可以通过激光照射条件,激光能量密度,重复率和温度的玻璃控制。纳米粒子的横截面的透射电子显微镜(TEM)图像显示,金属纳米团簇内的纳米粒子形成XeCl脉冲激光照射,一个独特的现象不同的TiO 2结晶通过常规的热处理的玻璃。由于含金属纳米团簇的纳米颗粒的形成是一种不同于以往关于XeCl激光辐照氧化物玻璃的现象,脉冲激光辐照和热处理的组合过程将打开各种各样的光学玻璃器件。
We report the fabrication of nanoparticles that contain metal nanoclusters at the surface of the CaO-Bi(2)O(3)-B(2)O(3)-Al(2)O(3)-TiO2 glass using XeCl laser irradiation. We have demonstrated that the surface morphology such as that containing nanoparticles or a smooth flat surface can be controlled by laser irradiation conditions; the laser fluence, repetition rate, and temperature of the glass. The transmission electron microscope (TEM) images of the cross section of the nanoparticles show that the metal nanoclusters were formed inside the nanoparticle by XeCl pulsed laser irradiation, a unique phenomenon different from TiO2-crystallization achieved by conventional heat-treatment of the glass. Since formation of nanoparticles containing metal nanocluster is a phenomenon different from previous papers about XeCl laser irradiation of oxide glasses, the combined process of pulsed laser irradiation and heat-treatment will open a wide variety of optical glass devices.
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