Subcomponent self-assembly of polymer chains based on dynamic and geometrical coordination diversity of the first row transition metal ions
Subcomponent self-assembly of polymer chains based on dynamic and geometrical coordination diversity of the first row transition metal ions
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基于第一排过渡金属离子动态和几何配位多样性的聚合物链子组分自组装
DOI：
10.1039/c3py01111a
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发表时间：
2014-01
影响因子：
4.6
通讯作者：
Dujin Wang
中科院分区：
文献类型：
--
作者：
Xuewen Wu;Na Xu;Zhengguang Zhu;Yuanli Cai;Ying Zhao;Dujin Wang
The subcomponent self-assembly of polymer chains based on the dynamic/geometrical coordination diversity of first row transition metal ions is reported. A well-defined NH2-functional hydrophilic block copolymer, Ni(II), Cu(II) and Zn(II) and a salicylaldehyde derivative are selected as subcomponents. The imine formation and self-assembly are followed using 1H NMR, DLS, GPC, and UV-vis spectroscopy. The results demonstrate that the subcomponent self-assembly strongly depends on the coordination stability constants and geometries of these metal ions. Ni(II) induces interchain coordination, and rapid phase transition to macro-phase separation but with the lowest autocatalysis efficiency. However, Cu(II) ions induce intrachain coordination with the most remarkable autocatalysis, and the delaying of the phase transition to form well-defined hybrid nanoparticles. The behaviour with Zn(II) ions is in between that with Ni(II) and Cu(II) ions. This striking differentiation demonstrates that the dynamic/geometrical coordination diversity of the abundant first row transition metal ions effectively control the subcomponent self-assembly of polymer chains, and thus the hierarchical nanostructures of dative metal–polymer hybrid functional materials.
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影响因子：
--
作者：
S. Zarra;J. Clegg;J. Nitschke
通讯作者：
S. Zarra;J. Clegg;J. Nitschke
影响因子：
64.8
作者：
D. Mellor;L. Maley
通讯作者：
D. Mellor;L. Maley
影响因子：
4.6
作者：
Guhuan Liu;Hui Shi;Yuru Cui;Jianyu Tong;Ying Zhao;Dujing Wang;Yuanli Cai
通讯作者：
Guhuan Liu;Hui Shi;Yuru Cui;Jianyu Tong;Ying Zhao;Dujing Wang;Yuanli Cai
影响因子：
20.6
作者：
S. Yamada;A. Takeuchi
通讯作者：
S. Yamada;A. Takeuchi
影响因子：
4.6
作者：
H. Hoss;H. Elias
通讯作者：
H. Hoss;H. Elias