Titanomagnetite – Silicate Melt Oxybarometry

Titanomagnetite – Silicate Melt Oxybarometry
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钛磁铁矿 – 硅酸盐熔融氧压计

DOI:
10.1002/9781119473206.ch18
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发表时间:
--
期刊:
Magma Redox Geochemistry
影响因子:
--
通讯作者:
Audétat A.
Audétat A.
中科院分区:
--
文献类型:
--
作者:
Arató R;Audétat A.

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岩浆的氧化态是岩浆作用中一个最重要的参数。虽然存在各种技术来重建岩浆的氧化状态,但这项任务仍然具有挑战性,特别是在侵入岩的情况下。钛磁铁矿是大多数岩浆岩中普遍存在的相,由于其能够掺入氧化还原敏感元素,因此可用于估计熔体的fO 2。传统的钛磁铁矿相关氧压法是基于钛磁铁矿-钛铁矿平衡对的测量,适用于大多数含有钛磁铁矿和钛铁矿的新鲜火山岩。然而,它不能用于在不含钛铁矿的岩浆中重建fO 2,或者在亚固相线条件下破坏/重置Fe-Ti氧化物。因此,开发了两种也可用于蚀变岩的方法。这两种方法基于(i)钒在钛磁铁矿和硅酸盐熔体之间的分配,以及(ii)铁和钛在钛磁铁矿和硅酸盐熔体之间的交换。这两个相通常作为斑晶中的包裹体保存下来,并且它们的原始组成可以通过LA-ICP-MS分析整个包裹体来获得。这样,钛磁铁矿-硅酸盐熔体分配系数和相应的fO 2可以确定,即使是缓慢冷却的火成岩,如花岗岩。
The oxidation state of magmas is a parameter of prime importance in magmatic processes. Although various techniques exist to reconstruct the oxidation state of magmas, this task remains challenging, particularly in the case of intrusive rocks. Titanomagnetite is a ubiquitous phase in most magmatic rocks and due to its ability to incorporate redox‐sensitive elements it can be used to estimate thefO2of the melt. Traditional titanomagnetite‐related oxybarometry is based on the measurement of titanomagnetite‐ilmenite equilibrium pairs, which is applicable to most fresh volcanic rocks containing both titanomagnetite and ilmenite. However, it cannot be used for reconstructingfO2in ilmenite‐free magmas, or in which Fe‐Ti oxides were destroyed/reset at subsolidus conditions. Therefore, two methods were developed that can be used also in altered rocks. These two methods are based on (i) the partitioning of vanadium between titanomagnetite and silicate melt, and (ii) the exchange of iron and titanium between titanomagnetite and silicate melt. Both of these phases are commonly preserved as inclusions in phenocrysts, and their original compositions can be obtained by analyzing entire inclusions by LA‐ICP‐MS. In this way, titanomagnetite–silicate melt partition coefficients and correspondingfO2can be determined even for slowly cooled igneous rocks such as granites.
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