Chemistry of polyvalent iodine.
Chemistry of polyvalent iodine.
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DOI：
10.1021/cr800332c
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发表时间：
2008-12
期刊：
影响因子：
62.1
通讯作者：
Stang, Peter J.
中科院分区：
文献类型：
--
作者：
Zhdankin, Viktor V.;Stang, Peter J.
从20世纪90年代初开始，多价碘有机化合物的化学经历了爆炸性的发展。对碘化合物的这种激增的兴趣主要是由于多价有机碘试剂的非常有用的氧化性质，以及它们的良性环境特性和商业可用性。碘（III）和碘（V）衍生物现在常规地用于有机合成中，作为复杂有机分子的各种选择性氧化转化的试剂。高价有机碘化学的几个领域最近引起了特别积极的兴趣和研究活动。这些领域，特别是，包括2-碘酰苯甲酸（IBX）和类似的氧化剂的碘（V）衍生物的合成应用，聚合物支撑的和可回收的多价碘试剂的开发和合成使用，有机碘化合物的催化应用，以及多价碘化合物的配合物和超分子组装体的结构研究。多价碘的化学以前已经在四本书1 -4和几篇综合评论论文中介绍过。5-17最近发表了许多关于特定类别的多价碘化合物及其合成应用的综述。18-61最值得注意的是关于[羟基（甲苯磺酰氧基）碘]苯的专门评论，41*嗯。edu）。
Starting from the early 1990s, the chemistry of polyvalent iodine organic compounds has experienced an explosive development. This surging interest in iodine compounds is mainly due to the very useful oxidizing properties of polyvalent organic iodine reagents, combined with their benign environmental character and commercial availability. Iodine (III) and iodine (V) derivatives are now routinely used in organic synthesis as reagents for various selective oxidative transformations of complex organic molecules. Several areas of hypervalent organoiodine chemistry have recently attracted especially active interest and research activity. These areas, in particular, include the synthetic applications of 2-iodoxybenzoic acid (IBX) and similar oxidizing reagents based on the iodine (V) derivatives, the development and synthetic use of polymer-supported and recyclable polyvalent iodine reagents, the catalytic applications of organoiodine compounds, and structural studies of complexes and supramolecular assemblies of polyvalent iodine compounds. The chemistry of polyvalent iodine has previously been covered in four books1-4 and several comprehensive review papers. 5-17 Numerous reviews on specific classes of polyvalent iodine compounds and their synthetic applications have recently been published. 18-61 Most notable are the specialized reviews on [hydroxy (tosyloxy) iodo] benzene, 41* Corresponding author (e-mail, vzhdanki@ d. umn. edu).
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影响因子：
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