Competitive sorption and selective sequence of Cu(II) and Ni(II) on montmorillonite: Batch, modeling, EPR and XAS studies

Competitive sorption and selective sequence of Cu(II) and Ni(II) on montmorillonite: Batch, modeling, EPR and XAS studies
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Cu(II) 和 Ni(II) 在蒙脱土上的竞争吸附和选择性序列:批量、建模、EPR 和 XAS 研究

DOI:
10.1016/j.gca.2015.06.020
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发表时间:
2015-10
影响因子:
5
通讯作者:
Wang Xiangke
Wang Xiangke
中科院分区:
地球科学1区
文献类型:
--
作者:
Yang Shitong;Ren Xuemei;Zhao Guixia;Shi Weiqun;Montavon Gilles;Grambow Bernd;Wang Xiangke

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特别地,来自图4的EPR谱“纯Mont”,包括噪声,看起来类似于谱“Mont/Cu(II)pH 8.0”和“Mont/Cu(II)/Ni(II)pH 8.0”,而光谱“Cu(NO3)2(aq)”和“Mont/Cu(II)pH6.0”与光谱“Mont/Cu(II)/Ni(II)pH5.0”和“Mont/Cu(II)/Ni(II)pH6.0”相似,此外,来自图8A的EXAFS光谱“Ni(OH)2(s)”和“Ni(NO3)2(aq)”看起来类似于来自一些作者等人先前在Geochimica et Cosmochimica Acta 75(2011)6520-6534 https://doi中发表的文章的图5A的光谱“β-Ni(OH)2”和“Ni(II)(aq)”。org/10.1016/j. gca。2011.08. 024.
Particularly, EPR spectrum “Pure Mont” from Figure 4, including the noise, appears similar to spectra “Mont/Cu (II) pH 8.0” and “Mont/Cu (II)/Ni (II) pH 8.0”, while spectra “Cu (NO 3) 2 (aq)” and “Mont/Cu (II) pH 6.0” appear similar to spectra “Mont/Cu (II)/Ni (II) pH 5.0” and “Mont/Cu (II)/Ni (II) pH 6.0”.Moreover, EXAFS spectra “Ni (OH) 2 (s)” and “Ni (NO 3) 2 (aq)” from Figure 8A appear similar to spectra “β-Ni (OH) 2” and “Ni (II)(aq)” from Figure 5A of the article that some of the authors et al have previously published in Geochimica et Cosmochimica Acta 75 (2011) 6520–6534 https://doi. org/10.1016/j. gca. 2011.08. 024.
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