The coordination and polymerisation of cyclic 1,3-dienes by gold(I) cations.

The coordination and polymerisation of cyclic 1,3-dienes by gold(I) cations.
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金(I)阳离子对环状 1,3-二烯的配位和聚合。

DOI:
10.1039/c1cc16193h
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发表时间:
2012
影响因子:
4.9
通讯作者:
C. A. Russell
C. A. Russell
中科院分区:
化学2区
文献类型:
--
作者:
R. A. Sanguramath;S. Patra;Michael J. Green;C. A. Russell

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环戊二烯和1,3-环己二烯容易通过[LAu][X]聚合。与特定的辅助配体聚合被抑制,并涉及Au(I)阳离子η(2)键CpH的分子物种被分离,其结构在固态和溶液中进行了探测。
Cyclopentadiene and 1,3-cyclohexadiene are readily polymerised by [LAu][X]. With specific ancillary ligands polymerisation was suppressed and a molecular species involving an Au(I) cation η(2)-bonding CpH was isolated and whose structure was probed in both the solid state and in solution.
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