Metal-organic frameworks as a tunable platform for designing functional molecular materials.
Metal-organic frameworks as a tunable platform for designing functional molecular materials.
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DOI：
10.1021/ja308229p
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发表时间：
2013-09-11
影响因子：
15
通讯作者：
Lin, Wenbin
中科院分区：
文献类型：
--
作者：
Wang, Cheng;Liu, Demin;Lin, Wenbin
金属有机骨架（MOFs），也称为配位聚合物，代表了一类有趣的结晶分子材料，它们是通过结合金属连接点和桥接配体合成的。M0 F合成的模块化性质和温和的条件允许许多M0 F的合理结构设计和通过组成构件并入各种官能度。由此产生的设计师MOFs已经显示出在许多领域的应用前景，包括气体存储/分离，非线性光学/铁电，催化，能量转换/存储，化学传感，生物医学成像和药物输送。MOF的结构-性质关系也可以通过利用其详细原子结构的知识来容易地建立，这使得能够针对所需应用微调其功能。通过分子合成和晶体工程的结合，MOFs为功能材料的合理和精确设计提供了前所未有的机会。
Metal-organic frameworks (MOFs), also known as coordination polymers, represent an interesting class of crystalline molecular materials that are synthesized by combining metal-connecting points and bridging ligands. The modular nature of and mild conditions for MOF synthesis have permitted the rational structural design of numerous MOFs and the incorporation of various functionalities via constituent building blocks. The resulting designer MOFs have shown promise for applications in a number of areas, including gas storage/separation, nonlinear optics/ferroelectricity, catalysis, energy conversion/storage, chemical sensing, biomedical imaging, and drug delivery. The structure-property relationships of MOFs can also be readily established by taking advantage of the knowledge of their detailed atomic structures, which enables fine-tuning of their functionalities for desired applications. Through the combination of molecular synthesis and crystal engineering MOFs thus present an unprecedented opportunity for the rational and precise design of functional materials.
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影响因子：
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作者：
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