A Brief Survey of our Contribution to Stable Carbene Chemistry.

A Brief Survey of our Contribution to Stable Carbene Chemistry.
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DOI:
10.1021/om200650x
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发表时间:
2011-10-24
期刊:
影响因子:
2.8
通讯作者:
Bertrand G
Bertrand G
中科院分区:
化学2区
文献类型:
--
作者:
Martin D;Melaimi M;Soleilhavoup M;Bertrand G

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这个个人帐户总结了我们的工作,从1988年发现第一个稳定的卡宾开始,直到最近分离出介离子卡宾。它解释了为什么我们已经把我们的重点从无环到环状卡宾,并表明,这些稳定的物种不仅限于过渡金属的配体的作用,但它们也是强大的试剂的小分子的活化,并为高活性的抗磁性和顺磁性物种的稳定。
This personal account summarizes our work, beginning with the discovery of the first stable carbene in 1988 up until the recent isolation of mesoionic carbenes. It explains why we have moved our focus from acyclic to cyclic carbenes, and shows that these stable species are not limited to the role of ligand for transition metals, but that they are also powerful agents for the activation of small molecules, and for the stabilization of highly reactive diamagnetic and paramagnetic species.
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