An Asymptotic Theory for the Re-Equilibration of a Micellar Surfactant Solution

An Asymptotic Theory for the Re-Equilibration of a Micellar Surfactant Solution
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胶束表面活性剂溶液再平衡的渐近理论

DOI:
10.1137/110842089
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发表时间:
2012
影响因子:
1.9
通讯作者:
Griffiths I
Griffiths I
中科院分区:
数学4区
文献类型:
--
作者:
Griffiths I

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Micellar surfactant solutions are characterized by a distribution of aggregates made up predominantly of premicellar aggregates (monomers, dimers, trimers, etc.) and a region of proper micelles close to the peak aggregation number, connected by an intermediate region containing a very low concentration of aggregates. Such a distribution gives rise to a distinct two-timescale re-equilibration following a system dilution, known as theandprocesses, whose dynamics may be described by the Becker–Döring equations. We use a continuum version of these equations to develop a reduced asymptotic description that elucidates the behavior during each of these processes.
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