Detection of rutin at DNA modified carbon paste electrode based on a mixture of ionic liquid and paraffin oil as a binder
Detection of rutin at DNA modified carbon paste electrode based on a mixture of ionic liquid and paraffin oil as a binder
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以离子液体和石蜡油为粘合剂的DNA修饰碳糊电极检测芦丁
DOI：
10.1007/s00604-010-0380-7
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发表时间：
2010-05
影响因子：
5.7
通讯作者：
中科院分区：
文献类型：
--
作者：
A DNA-modified carbon paste electrode (DNA-CPIE) was designed by using a mixture of the ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate and paraffin oil as the binder. The electrochemistry of rutin at the DNA-CPIE was investigated by cyclic voltammetry and differential pulse voltammetry. Rutin exhibits a pair of reversible redox peaks in buffer solutions of pH 3.0, and respective electrochemical parameters are established. Under the optimal conditions, the oxidative peak current is linear with the concentration of rutin in the range from 8 × 10−9to 1 × 10−5mol L−1, and the detection limit is 1.3 × 10−9mol L−1(at S/N = 3). The electrode exhibits higher sensitivity compared to DNA modified carbon paste electrode without ionic liquid and better selectivity comparing with electrodes without DNA. It also showed good performance, stability, and therefore represents a viable method for the determination of rutin.
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