Flexible self-supporting supramolecular polymeric membranes consisting of 1,3,5-trisubstituted benzene derivatives synthesized by highly selective photocyclic aromatization of helical poly(phenylacetylene)s in the membrane state
Flexible self-supporting supramolecular polymeric membranes consisting of 1,3,5-trisubstituted benzene derivatives synthesized by highly selective photocyclic aromatization of helical poly(phenylacetylene)s in the membrane state
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由1,3,5-三取代苯衍生物组成的柔性自支撑超分子聚合物膜，通过膜状态下螺旋聚苯乙炔的高选择性光循环芳构化合成
DOI：
10.1016/j.polymer.2013.05.063
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发表时间：
2013-08
期刊：
影响因子：
4.6
通讯作者：
Kaneko, Takashi
中科院分区：
文献类型：
--
作者：
Oniyama, Yoshiyuki;Tsutsuba, Toyokazu;Teraguchi, Masahiro;Kaneko, Takashi
已经实现了获得仅由1，3，5-三取代苯衍生物组成的柔性自支撑超分子聚合物膜，所述1，3，5-三取代苯衍生物通过具有柱状结构的相应聚（取代苯乙炔）的高选择性光环芳构化制备。通过在聚合物（单体）中引入羟基或亚苯基，提高了自支撑超分子聚合物膜的柔韧性。强度提高的原因有两个：1）引入了柱间氢键; 2）提高了柱内堆积程度。这种强度取决于作为模板的起始聚合物的结构。
It has been achieved to obtain flexible self-supporting supramolecular polymeric membranes consisting of only 1,3,5-trisubstituted benzene derivatives prepared by highly selective photocyclic aromatization of the corresponding poly (substituted phenylacetylene)s having a columnar structure. The flexibilities of the self-supporting supramolecular polymeric membranes were enhanced by introducing hydroxyl groups or phenylene groups to the starting polymers (monomers). There were two reasons for the enhanced strength: 1) introduction ofintercolumnar hydrogen bonds and 2) enhancement of the degree ofintracolumnar stackings. This strength depended on the structure of the starting polymers which functioned as a template.
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影响因子：
--
作者：
Isao Yoshikawa;Jun Sawayama;K. Araki
通讯作者：
Isao Yoshikawa;Jun Sawayama;K. Araki
影响因子：
1.6
作者：
Naoya Onishi;T. Aoki;T. Kaneko;M. Teraguchi;N. Sano;T. Masuda;M. Shiotsuki;F. Sanda
通讯作者：
Naoya Onishi;T. Aoki;T. Kaneko;M. Teraguchi;N. Sano;T. Masuda;M. Shiotsuki;F. Sanda
影响因子：
--
作者：
N. Yamada;Tsukasa Komatsu;Hirotsugu Yoshinaga;K. Yoshizawa;Susumu Edo;M. Kunitake
通讯作者：
N. Yamada;Tsukasa Komatsu;Hirotsugu Yoshinaga;K. Yoshizawa;Susumu Edo;M. Kunitake
影响因子：
5.5
作者：
Jia, Hongge;Teraguchi, Masahiro;Marwanta, Edy
通讯作者：
Marwanta, Edy
影响因子：
4.9
作者：
Y. Zang;T. Aoki;Lijia Liu;Yunosuke Abe;Yuriko Kakihana;M. Teraguchi;T. Kaneko
通讯作者：
Y. Zang;T. Aoki;Lijia Liu;Yunosuke Abe;Yuriko Kakihana;M. Teraguchi;T. Kaneko