Introduction of azetidinimine skeleton on C60
Introduction of azetidinimine skeleton on C60
复制标题
C60上氮杂环丁亚胺骨架的引入
DOI：
10.1002/hc.20703
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发表时间：
2011
影响因子：
0.3
通讯作者：
T. Akasaka
中科院分区：
文献类型：
--
作者：
Nobuaki Ueda;Hidefumi Nikawa;Yuta Takano;Midori O. Ishitsuka;T. Tsuchiya;T. Akasaka
氮杂环丁烷结构被引入到C60富勒烯使用的光化学反应与甲脒。合成了三种氮杂环丁烷富勒烯（2c-2 e），并利用1H、13 C和2D NMR、基质辅助激光解吸电离（MALDI）质谱、可见光谱和电化学对其结构进行了表征。单晶X射线晶体学分析表明，2 e的富勒烯笼上连接着一个独特的应变四元环，包括氮原子。© 2011 Wiley Periodicals，Inc. Heteroatom Chem 22：426-431，2011;在wileyonlinelibrary.com在线查看这篇文章。DOI 10.1002/hc.20703
The azacyclobutane structure is introduced into C60 fullerene using a photochemical reaction with formamidines. Three azetidinofullerenes (2c–2e) were synthesized; their molecular structures were characterized using 1H, 13C, and 2D NMR, matrix-assisted laser desorption ionization (MALDI) mass spectrometry, visible spectroscopy, and electrochemistry. Single crystal X-ray crystallographic analysis of 2e reveals a unique strained four-membered ring including nitrogen atom attached on the fullerene cage. © 2011 Wiley Periodicals, Inc. Heteroatom Chem 22:426–431, 2011; View this article online at wileyonlinelibrary.com. DOI 10.1002/hc.20703
影响因子：
5.2
作者：
Kevin M Kuhn;R. Grubbs
通讯作者：
Kevin M Kuhn;R. Grubbs