Off-resonant optical nonlinearities of phthalocyanine analogues: dihydroxy phosphorus(V) tetrabenzotriazacorroles

Off-resonant optical nonlinearities of phthalocyanine analogues: dihydroxy phosphorus(V) tetrabenzotriazacorroles
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酞菁类似物的非共振光学非线性:二羟基磷(V)四苯并三氮杂咯

DOI:
10.1016/j.optcom.2007.10.085
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发表时间:
2008-03
影响因子:
2.4
通讯作者:
--
中科院分区:
物理与天体物理3区
文献类型:
--
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利用飞秒简并四波混频(DFWM)技术测量了一系列酞菁类似物:未磺化的{P(OH)2 TBC}、磺化的{P(OH)2 TBCSn}和异丙氧基取代的{P(OH)2 TBC(OiPr)4}二羟基磷(V)四苯并三氮杂吡咯的三阶非线性光学性质。已经观察到超快的非共振光学响应,并且测得酞菁类似物的二阶超极化率高达(1.11-2.26)×10− 31 esu。
Third-order optical nonlinearity of a series phthalocyanine analogues, non-sulfonated {P(OH)2TBC}, sulfonated {P(OH)2TBCSn} and isopropoxyl substituted {P(OH)2TBC(OiPr)4} dihydroxy phosphorus(V) tetrabenzotriazacorroles were measured by femtosecond degenerate four-wave mixing (DFWM) technique at 800nm. Ultrafast off-resonant optical responses have been observed and the magnitude of the second-order hyperpolarizabilities of the phthalocyanine analogues were measured as high as (1.11–2.26)×10−31esu.
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