Monolithic Stationary Phases for Capillary Electrochromatography Based on Synthetic Polymers: Designs and Applications
Monolithic Stationary Phases for Capillary Electrochromatography Based on Synthetic Polymers: Designs and Applications
复制标题
基于合成聚合物的毛细管电色谱整体固定相：设计与应用
DOI：
10.1002/(sici)1521-4168(20000101)23:1
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发表时间：
2000
期刊：
影响因子：
--
通讯作者：
J. Fréchet
中科院分区：
文献类型：
--
作者：
F. Švec;E. C. Peters;D. Sýkora;Cong Yu;J. Fréchet
整体材料已迅速成为毛细管电色谱（CEC）领域中公认的固定相形式。它们的原位制备方法的简单性和容易获得的化学物质的种类繁多使得整体分离介质成为填充有颗粒材料的毛细管柱的有吸引力的替代物。本文综述了在这一快速发展的领域工作的许多小组的贡献，重点是从合成聚合物制备的整体毛细管柱。详细介绍了用于制备整料的各种方法，并且在可用的情况下，显示了所得整料毛细管柱的材料性质。它们的色谱性能通过在各种模式下对不同分析物混合物的大量分离来证明。虽然详细的研究聚合物的性质对整体式毛细管的分析性能的影响仍然很少在这个早期阶段的发展，这篇评论也讨论了一些重要的关系，如孔径对分离性能的影响更详细。
Monolithic materials have quickly become a well-established stationary phase format in the field of capillary electrochromatography (CEC). Both the simplicity of their in situ preparation method and the large variety of readily available chemistries make the monolithic separation media an attractive alternative to capillary columns packed with particulate materials. This review summarizes the contributions of numerous groups working in this rapidly growing area, with a focus on monolithic capillary columns prepared from synthetic polymers. Various approaches employed for the preparation of the monoliths are detailed, and where available, the material properties of the resulting monolithic capillary columns are shown. Their chromatographic performance is demonstrated by numerous separations of different analyte mixtures in variety of modes. Although detailed studies of the effect of polymer properties on the analytical performance of monolithic capillaries remain scarce at this early stage of their development, this review also discusses some important relationships such as the effect of pore size on the separation performance in more detail.
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影响因子：
7.4
作者：
Peters, EC;Petro, M;Fréchet, JMJ
通讯作者：
Fréchet, JMJ
影响因子：
7.4
作者：
P. Wright;Andee Lister;J. Dorsey
通讯作者：
P. Wright;Andee Lister;J. Dorsey
影响因子：
4.1
作者：
Asiaie, R;Huang, X;Horváth, C
通讯作者：
Horváth, C
影响因子：
7.4
作者：
E. C. Peters;M. Petro;F. Švec;J. Fréchet
通讯作者：
E. C. Peters;M. Petro;F. Švec;J. Fréchet
影响因子：
4.1
作者：
Huang, X;Zhang, J;Horváth, C
通讯作者：
Horváth, C