A New Piezochromic Fluorescence and Aggregation-Induced Emission Compound Containing Tetraphenylethylene and Triphenylamine Moieties with Morphology-alterable Property

A New Piezochromic Fluorescence and Aggregation-Induced Emission Compound Containing Tetraphenylethylene and Triphenylamine Moieties with Morphology-alterable Property
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一种新型压致变色荧光和聚集诱导发射化合物,含有四苯乙烯和三苯胺部分,具有形态可变特性

DOI:
10.1007/s10895-011-0990-4
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发表时间:
2012-03
影响因子:
2.7
通讯作者:
Xu, Jia-rui
Xu, Jia-rui
中科院分区:
化学4区
文献类型:
--
作者:
Zhou, Xie;Li, Hai-yin;Chi, Zhen-guo;Xu, Bing-jia;Zhang, Xi-qi;Zhang, Yi;Liu, Si-wei;Xu, Jia-rui

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合成了一种具有聚集诱导发射(AIE)效应和形态可变发射性能的新型压电变色荧光(PCF)化合物。得到了无定形和晶态的聚集体,其光谱性质和形态结构在压制(熏蒸)或退火后可逆地重复显示。压电致变色的荧光性质是通过晶态-非晶态相变产生的。结果表明,具有扭曲螺旋桨构象的AIE化合物具有PCF活性。AIE和PCF之间建立的共同关系将指导研究人员识别和合成更多的压电荧光材料。
A novel piezochromic fluorescent (PCF) compound with aggregation-induced emission (AIE) effect and morphology-alterable emission property was developed. The amorphous and crystalline aggregates were obtained, and their spectroscopic properties and morphological structures were reversibly and repeatedly exhibited upon pressing (fuming) or annealing. The piezochromic fluorescent nature was generated through crystalline-amorphous phase transformation. It was proposed that AIE compounds existing a twisted propeller-shaped conformation will exhibit PCF activity. The common relationship betweeen AIE and PCF established will guide researchers in identifying and synthesizing more piezochromic fluorescent materials.
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