Thin solid state reference electrodes for use in solid polymer electrolytes
Thin solid state reference electrodes for use in solid polymer electrolytes
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用于固体聚合物电解质的薄固态参比电极
DOI:
10.1016/j.elecom.2014.03.005
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发表时间:
2014
影响因子:
5.4
通讯作者:
Smith G
中科院分区:
文献类型:
--
作者:
Smith G
This paper reports two low-profile (~ 10 μm thick) solid state reference electrodes for use in solid polymer electrolytes. The thin, open geometry of the electrodes enables close positioning between the working and counter electrodes. The first electrode uses the palladium hydride (Pd|PdHx) couple (PHRE), and the second utilises the hydrous iridium oxide (IrOx·yH2O|IrOa·bH2O) couple (IORE). To our knowledge this is the first use of the latter as a reference electrode. The PHRE had a stable potential of + 70 mV vs RHE with a 4 mV h− 1drift and two hour lifetime, whilst the IORE gave a potential of + 847 mV vs RHE with a drift of 0.3 mV h− 1and no deterioration after 24 h of use. The use of these reference electrodes in a three-electrode solid state cell and a fuel cell is demonstrated.
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DOI:
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发表时间:
1998
期刊:
影响因子:
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作者:
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DOI:
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发表时间:
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DOI:
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发表时间:
1995
期刊:
影响因子:
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作者:
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