Surface Tension and Parachor Measurement of Low-Global Warming Potential Working Fluid cis-1-Chloro-2,3,3,3-tetrafluoropropene (R1224yd(Z))

Surface Tension and Parachor Measurement of Low-Global Warming Potential Working Fluid cis-1-Chloro-2,3,3,3-tetrafluoropropene (R1224yd(Z))
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低全球变暖潜势工作液顺式 1-氯-2,3,3,3-四氟丙烯 (R1224yd(Z)) 的表面张力和 Parachor 测量

DOI:
10.1021/acs.jced.9b00613
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发表时间:
2019
影响因子:
--
通讯作者:
Iwasaki Shun
Iwasaki Shun
中科院分区:
工程技术3区
文献类型:
--
作者:
Kondou Chieko;Higashi Yukihiro;Iwasaki Shun

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本文介绍了顺-1-氯-2,3,3,3-四氟丙烯(R1224yd(Z), (Z) -CF3CF = CHCl)在266-340 K温度范围内的精确表面张力测量。测量采用微分毛细管上升法。95%置信度的扩展不确定度估计在0.19 mN·m-1以内。根据实测数据,得到了表示温度依赖性的范德瓦尔斯型相关:σ = 57.02 (1 -T /428.69)1.265[mN·m-1]。另外,降落伞[PR1224yd(Z)]确定为207。Miller和Thodos (Ind. Eng.)预测的表面张力值。化学。基金,1963,2.1,78),Miqueu等人(流体ph平衡,2000,172,169),和Di Nicola等人(Int.)。j . Thermophys。(2011,34,2243),以及使用降落伞法获得的结果,与测量数据吻合良好。
This article presents the accurate surface tension measurement ofcis-1-chloro-2,3,3,3-tetrafluoropropene (R1224yd(Z), (Z)–CF3CF═CHCl), over the temperature range 266–340 K. The measurement was performed using the differential capillary rise. The expanded uncertainty at 95% confidence was estimated to be within 0.19 mN·m–1. Based on the measured data, the van der Waals-type correlation expressing the temperature dependence was obtained as σ = 57.02 (1 –T/428.69)1.265[mN·m–1]. In addition, the parachor [PR1224yd(Z)] was determined as 207. The surface tension values predicted by Miller and Thodos (Ind. Eng. Chem. Fund.,1963,2.1,78), Miqueu et al. (Fluid Ph. Equilibria,2000,172,169), and Di Nicola et al. (Int. J. Thermophys.,2011,34,2243), as well as those obtained using the parachor method, were in good agreement with the measurement data.
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