Two new polyoxometalate-templated supramolecular compounds constructed by a new tridentate ligand 2,4,6-tris[1-(4-oxidroxypyridinium)-ylmethyl]-mesitylene

Two new polyoxometalate-templated supramolecular compounds constructed by a new tridentate ligand 2,4,6-tris[1-(4-oxidroxypyridinium)-ylmethyl]-mesitylene
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由新型三齿配体2,4,6-三[1-(4-氧化吡啶鎓)-基甲基]-均三甲苯构建的两种新型多金属氧酸盐模板超分子化合物

DOI:
10.1016/j.ica.2013.02.022
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发表时间:
2013-05
影响因子:
2.8
通讯作者:
Ma, Jian-Fang
Ma, Jian-Fang
中科院分区:
化学3区
文献类型:
--
作者:
Guo, Jiao;Yang, Jin;Liu, Ying-Ying;Ma, Jian-Fang

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Two novel compounds, namely, [(H2toym)4(Mo8O26)2]·15H2O (1) and [(H2toym)2(SiW12O40)]·6H2O (2) (toym=2,4,6-tris[1-(4-oxidroxypyridinium)-ylmethyl]-mesitylene), have been hydrothermally synthesized. Their structures have been determined by single-crystal X-ray diffraction analyses and further characterized by infrared spectra (IR), elemental analyses, powder X-ray diffraction (PXRD), thermogravimetric (TG) analyses, and UV–Vis absorption spectra. Compounds 1 and 2 exhibit new supramolecular networks templated by polyoxometalates (POMs). The “host” supramolecular networks with large pores are composed of the partly protonated toym ligands for 1 and 2. The “guest” POMs are located in the pores and dispersed between two organic layers in the complexes. The luminescent properties for 1 and 2 have been studied. In addition, compounds 1 and 2 exhibit photocatalytic activities for methylene blue (MB) degradation under UV.
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